Photochemically and Magneto Chemically Triggered Storage / Release of Solar Energy in Strained Organic Compounds

• Applicants: Professor Dr. Dirk M. Guldi; Professor Dr. Andreas Hirsch
• Subject Area: Physical Chemistry of Molecules, Liquids and Interfaces, Biophysical Chemistry
• Term: from 2017 to 2021
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 391585168

• Final Report Year: 2022

Final Report Abstract

No abstract available

Publications

• Anchoring of a Carboxyl-Functionalized Norbornadiene Derivative to an Atomically Defined Cobalt Oxide Surface. J. Phys. Chem. C 2017, 121, 11508–11518
  M. Schwarz, S. Mohr, T. Xu, T. Döpper, C. Weiß, K. Civale, A. Hirsch, A. Görling, J. Libuda
  (See online at https://doi.org/10.1021/acs.jpcc.7b02620)
• Catalytically Triggered Energy Releasefrom Strained Organic Molecules: The Surface Chemistry of Quadricyclane and Norbornadiene opn Pt(111). Chem. Eur. J. 2017, 23, 1613–1622
  U. Bauer, S. Mohr, T. Döpper, P. Bachmann, F. Späth, F. Düll, M. Schwarz, O. Brummel, L. Fromm, U. Pinkert, A. Görling, A. Hirsch, J. Bachmann, H. P. Steinrück, J. Libuda, C. Papp
  (See online at https://doi.org/10.1002/chem.201604443)
• Controlled Catalytic Energy Release of the Norbornadiene/Quadricyclane Molecular Solar Thermal Energy Storage System on Ni(111). J. Phys. Chem. C 2019, 123, 7654–7664
  U. Bauer, L. Fromm, C. Weiß, P. Bachmann, F. Späth, F. Düll, J. Steinhauer, W. Hieringer, A. Görling, A. Hirsch, et al.
  (See online at https://doi.org/10.1021/acs.jpcc.8b03746)
• Surface chemistry of 2,3-dibromosubstituted norbornadiene/quadricyclane as molecular solar thermal energy storage system on Ni(111). J. Chem. Phys. 2019, 150, 184706
  U. Bauer, L. Fromm, C. Weiß, F. Späth, P. Bachmann, F. Düll, J. Steinhauer, S. Matysik, A. Pominov, A. Görling, A. Hirsch, H.P. Steinrück, C. Papp
  (See online at https://doi.org/10.1063/1.5095583)
• Efficient Cyclization of the Norbornadiene‐Quadricyclane Interconversion Mediated by a Magnetic [Fe3O4−CoSalphen] Nanoparticle Catalyst. ChemPhotoChem 2020, 4, 52–58
  T. Luchs, P. Lorenz, A. Hirsch
  (See online at https://doi.org/10.1002/cptc.201900194)
• Photoswitchable Norbornadiene–Quadricyclane Interconversion Mediated by Covalently Linked C60. Chem. A Eur. J. 2020, 26, 5220–5230
  P. Lorenz, A. Hirsch
  (See online at https://doi.org/10.1002/chem.201904679)
• Molecular Solar Thermal Batteries through Combination of Magnetic Nanoparticle Catalysts and Tailored Norbornadiene Photoswitches. Chem. A Eur. J. 2021, 27, 4993–5002
  P. Lorenz, T. Luchs, A. Hirsch
  (See online at https://doi.org/10.1002/chem.202005427)
• Tunable Photoswitching in Norbornadiene (NBD)/Quadricyclane (QC) – Fullerene Hybrids. Chem. Eur. J. 2021, 27, 14501-14507
  P. Lorenz, F. Wullschläger, A. Rüter, B. Meyer, A. Hirsch
  (See online at https://doi.org/10.1002/chem.202102109)
• Solar Energy Storage: Competition between Delocalized Charge Transfer and Localized Excited States in the Norbornadiene to Quadricyclane Photoisomerization. J. Am. Chem. Soc 2022, 144, 153-162
  W. Alex, P. Lorenz, C. Henkel, T. Clark, A. Hirsch, D. M. Guldi
  (See online at https://doi.org/10.1021/jacs.1c04322)