Templatgesteuerte Synthese von komplexen Monomer-Sequenzen in Kettenpolymerisationen

• Antragsteller: Dr. Niels ten Brummelhuis
• Fachliche Zuordnung: Präparative und Physikalische Chemie von Polymeren ; Polymermaterialien
• Förderung: Förderung von 2014 bis 2019
• Projektkennung: Deutsche Forschungsgemeinschaft (DFG) - Projektnummer 260112213

• Erstellungsjahr: 2019

Zusammenfassung der Projektergebnisse

The DFG Research Grant aimed to use templating effects to control the sequence of the building blocks in polymer chains. Such a control should be able to give us more control over the properties of these materials. Templating, which is achieved by preorganization of the monomers, was achieved by the binding of two different monomers in a single cavity of a cyclodextrin moiety, by using hydrogen bonding of certain solvents and by using covalently bound templating moieties. The work provides a number of different methods to prepare polymers with tailored structures, and these methods could therefore be used to study the influence of the monomer sequence on the properties of the polymers, to create functional materials, etc.

Projektbezogene Publikationen (Auswahl)

• Controlling Monomer‐Sequence using Supramolecular Templates, Polym. Chem. 2015, 6, 654‐667
  N. ten Brummelhuis
  (Siehe online unter https://doi.org/10.1039/c4py01522c)
• Polymerization of Ternary Inclusion Complexes of Interacting Monomer Pairs in γ‐Cyclodextrin, Macromolecules 2016, 49, 6879‐6887
  N. ten Brummelhuis, M.T. Heilmann
  (Siehe online unter https://doi.org/10.1021/acs.macromol.6b01203)
• Synthesis and Functionalization of Periodic Copolymers, Polymers 2017, 9, 166
  F. Kubatzki, L. Al‐Shok, N. ten Brummelhuis
  (Siehe online unter https://doi.org/10.3390/polym9050166)