Detailseite
Projekt
Iron dynamics in earth mantle minerals probed by Mössbauer spectroscopy using synchrotron radiation
Antragsteller
Professor Dr. Volker Schünemann
Fachliche Zuordnung
Mineralogie, Petrologie und Geochemie
Förderung
Förderung von 2006 bis 2010
Projektkennung
Deutsche Forschungsgemeinschaft (DFG) - Projektnummer 24982785
Exploring the dynamic properties of iron minerals contained in the earth mantle enables to understand seismologic data on the microscopic scale. Mössbauer spectroscopy is the method of choice if electronic and dynamic properties of iron containing minerals have to be investigated. We therefore propose to measure the dynamic properties of the iron containing minerals olivine, pyroxene, iron silicate perovskite and ferropericlase by Mössbauer spectroscopy under high-pressure with synchrotron radiation. Nuclear inelastic scattering (NIS) and accompanying quantum mechanical model calculations employing density functional theory (DFT) will deliver the phonon density of states of the minerals under investigation both experimentally and theoretically. In this way we will obtain information on the velocity of sound in these materials under high pressure conditions. Parallel to the NIS experiments we will perform nuclear forward scattering (NFS) which will yield information on the iron valence state and the corresponding iron mineral phases. This is especially interesting in the region of phase transitions which are responsible for discontinuities in the seismic response of the earth mantle.
DFG-Verfahren
Schwerpunktprogramme
