GRK 1582:  Fluorine as Key Element: Discovering Innovative Synthetic Concepts to Generate Novel Molecules with Unique Properties

• Subject Area: Molecular Chemistry
• Term: from 2009 to 2018
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 99919608

• Final Report Year: 2019

Final Report Abstract

Fluor nimmt aufgrund seiner einzigartigen Eigenschaften unter den Elementen des chemischen Periodensystems eine Sonderrolle ein. Seine Besonderheiten verleihen chemischen Verbindungen, die daraus synthetisiert bzw. mit Fluorsubstituenten modifiziert werden, besondere Eigenschaften. Die Fluorchemie ist ein wichtiger Teilbereich der chemischen Industrie und ermöglichte die Entwicklung zahlreicher neuer Materialien und Wirkstoffe, die aus unserem täglichen Leben nicht mehr wegzudenken sind. Die besonderen Eigenschaften von Fluor erfordern spezielle Methoden und Strategien zur Darstellung seiner Verbindungen. Trotz der hohen Praxisrelevanz ist die Anzahl von Arbeitsgruppen in Deutschland, die sich überwiegend mit Fluorchemie beschäftigen, sehr gering. Zudem ist Fluorchemie kein zentraler Bestandteil des Ausbildungsprogramms für Chemiker an deutschen Hochschulen. Konzepte und Methoden der Fluorchemie sowie viele experimentelle Techniken zur gezielten Einführung fluorierter Funktionalitäten und zur sicheren Handhabung fluorierter Verbindungen sind den meisten Studierenden fremd. Um dem entgegenzuwirken und weiter zukunftsweisende Forschung auf Gebieten der Fluorchemie auf international führendem Niveau zu ermöglichen, wurde 2009 das Gruduiertenkolleg „Fluor als Schlüsselelement“ gegründet. Berlin galt schon lange als Zentrum der deutschen Fluorchemie. Es gibt hier eine ungewöhnlich hohe Anzahl von Arbeitsgruppen, die an unterschiedlichen Aspekten der Fluorchemie forschen. Bereits bei Antragstellung zur Einrichtung des GRK 1582 befassten sich an FUB und HUB mehr als 12 Arbeitsgruppen mit Fluorchemie. Während der ersten Förderperiode sind noch weitere Arbeitsgruppen, auch an der TUB, hinzugekommen, die die Eigenschaften fluorierter Verbindungen durch vielfältige Methoden untersuchen. Die Bündelung der Expertise, die von der Synthese von Elementfluoriden über die Katalyse, Theorie bis hin zur Materialforschung und biologischen Chemie reicht, bildete eine ideale Plattform für die Etablierung eines Ausbildungsprogramms. Von 2009–2018 haben 20 Arbeitsgruppen an drei Berliner Universitäten im GRK gearbeitet. Der Fokus der Forschungsprojekte lag auf der Erarbeitung neuer synthetischer Zugangsmöglichkeiten zu fluorhaltigen Molekülen und auf der Untersuchung von Struktur-Eigenschafts-Beziehungen. Durch intensive Kooperationen und interdisziplinäre Promotionsprojekte waren die wissenschaftlichen Teilbereiche eng miteinander verknüpft. 81 Studierende haben im GRK promoviert und ein umfassendes Verständnis der Eigenschaften fluorierter Verbindungen erlangt. Ein Kernelement des Graduiertenkollegs waren die Kollegseminare. Insgesamt 140 namhafte Wissenschaftler/innen aus 21 Ländern und allen Gebieten der Fluorchemie waren bei diesen Seminaren unsere Gäste und haben über ihre aktuellen Forschungsprojekte berichtet bzw. im Rahmen von Ringvorlesungen wichtige Grundlagen der Fluorchemie vermittelt. Persönliche Gespräche und wissenschaftliche Diskussionen über Forschungsergebnisse führten zu einem intensiven Austausch der Studierenden mit Gästen. Feste Bestandteile der Kollegseminare waren Vorträge von Gästen aus der Industrie sowie Ergebnisberichte der Promovierenden zum Stand ihrer Promotionsprojekte. Das Ausbildungsprogramm wurde ergänzt durch die einmal jährlich stattfindenden Workshops, die von Promovierenden selbständig organisiert wurden. Die Gründung des „Solvay-Fluor-Laboratoriums“ ermöglichte es akademische Grundlagenforschung mit industriell relevanten Themen zu verknüpfen. In enger Zusammenarbeit mit den beiden Dachorganisationen für Graduiertenprogramme, der Dahlem Research School und der Humboldt Graduate School, haben sich unsere Studierenden wichtige Schlüsselqualifikationen angeeignet, die auf die nächsten Karriereschritte in Akademie und Industrie vorbereiteten. Internationale Stellenausschreibungen, zahlreiche Auftritte von Studierenden und ArbeitsgruppenleiterInnen bei Konferenzen sowie mehr als 280 Publikationen des GRK haben zu einer weltweiten Sichtbarkeit geführt. Die interdisziplinäre Ausrichtung des Kollegs und die vielen durch die Antragsteller etablierten Kooperationen mit international führenden Wissenschaftler/innen führten zu erfolgreichen Zusammenarbeiten. Eine international ausgerichtete, interdisziplinäre Ausbildung zum Thema Fluorchemie wurde etabliert, die nun im Rahmen einer Vorlesungsreihe zu Grundlagen der Fluorchemie, ebenso wie ein Praktikums-Modul zur Vermittlung wichtiger Arbeitstechniken in die Chemie-Masterausbildung von FUB und HUB fest integriert werden konnten. Die Finanzierung dieses Graduiertenkollegs durch die DFG ermöglichte nicht nur, dass die internationale Sichtbarkeit von Berlin als Zentrum der Fluorchemie im internationalen Maßstab klar manifestiert werden konnte, sondern auch generell die Fluorchemie in Deutschland gestärkt und um viele professionell ausgebildete Absolventen bereichert wurde.

Publications

• Synthesis of enantiomerically pure (2S,3S)-5,5,5-trifluoroisoleucine and (2R,3S)-5,5,5-trifluoro-alloisoleucine, Beilstein J. Org. Chem. 2013, 9, 2009
  H. Erdbrink, E. K. Nyakatura, S. Huhmann, U. I. M. Gerling, D. Lentz, B. Koksch, C. Czekelius
  (See online at https://doi.org/10.3762/bjoc.9.236)
• A Highly Reactive Rhodium(I)–Boryl Complex as a Useful Tool for C-H Bond Activation and Catalytic C-F Bond Borylation, Angew. Chem. 2010, 122(23), 4039; Angew. Chem. Int. Ed. 2010, 49, 3947
  M. Teltewskoi, J. A. Panetier, S. A. Macgregor, T. Braun
  (See online at https://doi.org/10.1002/ange.201001070 https://doi.org/10.1002/anie.201001070)
• Approaches towards identifying preferred interaction partners of fluorinated amino acids within the hydrophobic environment of a dimeric coiled coil peptide, Org. Biomol. Chem. 2010, 8, 1382
  T. Vagt, E. Nyakatura, C. Jäckel, B. Koksch
  (See online at https://doi.org/10.1039/B917205J)
• Charge Transfer via the Dative N-B Bond and Dihydrogen Contacts. Experimental and Theoretical Electron Density Studies of Small Lewis Acid-Base Adducts, J. Phys. Chem. A, 2010, 114, 10185
  S. Mebs, S. Grabowsky, D. Förster, R. Kickbusch, M. Hartl, L. L. Daemen, W. Morgenroth, P. Luger, B. Paulus, D. Lentz
  (See online at https://doi.org/10.1021/jp100995n)
• Chemical aminoacylation of tRNAs with fluorinated amino acids for in vitro protein mutagenesis, J. Org. Chem. 2010, 6, 40
  S. Ye, A. A. Berger, D. Petzold, O. Reimann, B. Matt, B. Koksch, Beilstein
  (See online at https://doi.org/10.3762/bjoc.6.40)
• Fluorinated dienes in transition-metal chemistry – the rich chemistry of electron-poor ligands, Dalton Trans., 2010, 39(41), 9729
  M. F. Kühnel, D. Lentz
  (See online at https://doi.org/10.1039/C0DT00097C)
• Size-Tunable Micron-Bubbles Based on Fluorous-Fluorous Interactions of Perfluorinated Dendritic Polyglycerols, Chem. Phys. Chem. 2010, 11(12), 2617
  M. Zieringer, A. Garcia-Bernabé, B. Costisella, H. Glatz, W. Bannwarth, R. Haag
  (See online at https://doi.org/10.1002/cphc.201000157)
• Three-Component Synthesis of Perfluoroalkyl- or Perfluoroaryl-Substituted 4-Hydroxypyridine Derivatives and their Palladium-Catalyzed Coupling Reactions, J. Org. Chem. 2010, 75(3), 726
  T. Lechel, J. Dash, P. Hommes, D. Lentz, H.-U. Reissig,
  (See online at https://doi.org/10.1021/jo9022183)
• Titankatalysierte C-F-Aktivierung von Fluoralkenen, Angew. Chem. 2010, 122(16), 2995
  M. F. Kühnel, D. Lentz
  (See online at https://doi.org/10.1002/ange.200907162)
• Autocatalytic formation of fluorinated ferrocenophanes from 1,1'-Bis(trifluorovinyl)ferrocene, Chem. Commun. 2011, 47, 7239
  M. Roemer, D. Lentz
  (See online at https://doi.org/10.1039/c1cc11812a)
• Catalytic C-H Bond Activation at Nanoscale Lewis Acidic Aluminium Fluorides: H/D Exchange Reactions at Aromatic and Aliphatic Hydrocarbons, Chem. Eur. J. 2011, 17, 14385
  M. H. G. Prechtl, M. Teltewskoi, A. Dimitrov, E. Kemnitz, T. Braun
  (See online at https://doi.org/10.1002/chem.201102853)
• Characterization of surfacial basic sites of sol gel-prepared alkaline earth fluorides by means of PulseTA, Thermochimica Acta 2011, 524, 170
  M. Feist, K. Teinz, S. Robles Manuel, E. Kemnitz
  (See online at https://doi.org/10.1016/j.tca.2011.07.010)
• Coherent control of the ultrafast dissociative ionization dynamics of bromochloroalkanes, Phys. Chem. Chem. Phys. 2011, 13(19), 8705
  J. Plenge, A. Wirsing, I. Wagner-Drebenstedt, I. Halfpap, B. Kieling, B. Wassermann, E. Rühl
  (See online at https://doi.org/10.1039/C0CP02742A)
• Cymantrene- and Ferrocene-Based Complexes with Perfluorinated Bridging Moieties, Organometallics 2011, 30(7), 2063
  M. Roemer, P. Schmiel, D. Lentz
  (See online at https://doi.org/10.1021/om2000053)
• Facile oxidative addition of water at iridium: reactivity of trans-[Ir(4-C5NF4)(H)(OH)(P(iPr)3)2] towards CO2 and NH3, Dalton Trans. 2011, 40, 6785
  P. Kläring, S. Pahl, T. Braun, A. Penner
  (See online at https://doi.org/10.1039/C1DT10173K)
• Four-Component Synthesis of Functionalized 2,2´-Bipyridines Based on the Blaise Reaction, Synlett 2011, 16, 2311
  P. Hommes, S. P. Jungk, H.-U. Reissig
  (See online at https://dx.doi.org/10.1055/s-0030-1260304)
• Highly selective metal fluoride catalysts for the dehydrohalogenation of 3-chloro-1,1,1,3-tetrafluorobutane, J. Catal. 2011, 282(1), 175
  K. Teinz, S. Wuttke, F. Börno, J. Eicher, E. Kemnitz
  (See online at https://doi.org/10.1016/j.jcat.2011.06.013)
• Inorganic-Organic Nanocomposites Based on Sol-Gel Derived Magnesium Fluoride, Nanoscale 2011, 3, 4774
  J. Noack, L. Schmidt, H.-J. Gläsel, M. Bauer, E. Kemnitz
  (See online at https://doi.org/10.1039/C1NR10843C)
• Metal fluoride materials with complex pore structure and organic functionality. Chem. 2011, 21, 334
  J. Noack, K. Teinz, F. Ch. Schaumberg, C. Fritz, S. Rüdiger, E. Kemnitz, J. Mater
  (See online at https://doi.org/10.1039/C0JM02204G)
• Metal hydride induced hydrodefluorination of fluorinated alkenes and allenes, Dissertation, Freie Universität Berlin, 2011
  Moritz F. Kühnel
  
• Sols of nanosized magnesium fluoride: formation and stabilisation of nanoparticles, J. Mater. Chem. 2011, 21, 15015
  J. Noack, F. Emmerling, H. Kirmse, E. Kemnitz
  (See online at https://doi.org/10.1039/C1JM11943E)
• Structure analysis of an amyloid forming model peptide by a systematic glycine- and proline scan, Biomacromolecules, 2011, 12, 2988
  U. I. M. Gerling, E. Brandenburg, H. v. Berlepsch, K. Pagel, B. Koksch
  (See online at https://doi.org/10.1021/bm200587m)
• Synthesis of fluorinated geminal diisocyanides stabilized on a transition metal, J. Fluorine Chem. 2011, 132(10), 719
  C. Frank, J. Krüger, D. Lentz
  (See online at https://doi.org/10.1016/j.jfluchem.2011.04.015)
• Bifunctional Nanoscopic Catalysts for the One-Pot Synthesis of (±)-Menthol from Citral, Top. Cat. 2012, 55, 680
  A. Negoi, K. Teinz, E. Kemnitz, St. Wuttke, V. I. Parvulescu, S. M. Coman
  (See online at https://doi.org/10.1007/s11244-012-9850-y)
• Bulky-Alkyl-Substituted Bis(trifluorovinyl)ferrocenes: Redox-Autocatalytic Formation of Fluorinated Ferrocenophanes, Organometallics 2012, 31(4), 1500
  M. Roemer, D. Heinrich, Y. K. Kang, Y. K. Chung, D. Lentz
  (See online at https://doi.org/10.1021/om2009765)
• Conjugate hydrotrifluoromethylation of α,β-unsaturated acryl-oxazolidinones: synthesis of chiral fluorinated amino acids, Org. Biomol. Chem. 2012, 10, 8583
  H. Erdbrink, I. Peuser, U. I. M. Gerling, D. Lentz, B. Koksch, C. Czekelius
  (See online at https://doi.org/10.1039/C2OB26810H)
• Darstellung höchstwertiger Übergangsmetall-Chloride und Versuche zur Darstellung von Iridium-Xenon Komplexen, Dissertation, Freie Universität Berlin, 2012
  Farhad Tamadon
  (See online at https://doi.org/10.17169/refubium-8721)
• Electron correlation contribution to the physisorption of CO on MgF2(110), J. Chem. Phys. 2012, 136, 124117
  L. Hammerschmidt, C. Müller, B. Paulus
  (See online at https://doi.org/10.1063/1.3697867)
• Electron-poor N-substituted imide-fused corannulenes, Chem. Commun. 2012, 48, 6520
  B. M. Schmidt, B. Topolinski, Ph. Roesch, D. Lentz
  (See online at https://doi.org/10.1039/C2CC32643D)
• Elektronische Eigenschaften trifluormethylierter Corannulene, Angew. Chem. 2012, 124(45), 11548; Electronic Properties of Trifluoromethylated Corannulenes, Angew. Chem. Int. Ed. 2012, 51(45), 11385
  B. M. Schmidt, S. Seki, B. Topolinski, K. Ohkubo, S. Fukuzumi, H. Sakurai, D. Lentz
  (See online at https://doi.org/10.1002/ange.201205757 https://doi.org/10.1002/anie.201205757)
• Ferrocenes with Perfluorinated Side Chains and Ferrocenophanes with Fluorinated Handles, Chem. Eur. J. 2012, 18(11), 3371
  M. Roemer, Y. K. Kang, Y. K. Chung, D. Lentz
  (See online at https://doi.org/10.1002/chem.201102508)
• Fluorinated amino acids: Compatibility with native protein structures and effects on protein-protein interactions, Chem. Soc. Rev. 2012, 41, 2135
  M. Salwiczek, E. K. Nyakatura, U. I. M. Gerling, S. Ye, B. Koksch
  (See online at https://doi.org/10.1039/C1CS15241F)
• Halogenated Benzene Cation Radicals, Chem. Eur. J. 2012, 118, 6644
  M. J. Molski, D. Mollenhauer, S. Gohr, B. Paulus, M. A. Khanfar, H. Shorafa, S. H. Strauss, K. Seppelt
  (See online at https://doi.org/10.1002/chem.201102960)
• Influence of Perfluorinated Substituents on the Nucleophilic Reactivities of Silyl Enol Ethers, Org. Lett. 2012, 14(15), 3990
  H. A. Laub, D. Gladow, H.-U. Reissig, H. Mayr
  (See online at https://doi.org/10.1021/ol301766w)
• Inorganic-organic composite sys-tems based on nanoscopic aluminium fluoride, Dissertation, Humboldt-Universität zu Berlin, 2012
  Carsten Fritz
  
• Investigation of Higher Fullerenes: Trifluoromethylated Deriva-tives of C84 Cage Isomers, Dissertation, Humboldt-Universität zu Berlin, 2012
  Kai-Chin Chang
  
• Microfluidic synthesis of monodisperse porous microspheres with size-tunable pores, Soft Matter 2012, 8, 10636
  M. Zieringer, O. Wagner, J. N. Wilking, A. Abbaspourrad, R. Haag, D. A. Weitz,
  (See online at https://doi.org/10.1039/C2SM25694K)
• n-Pentane hydroisomerization catalyzed by metals supported on nanoscopic aluminium trifluoride, Cat. Com. 2012, 26, 235
  O. Machynskyy, D. Lomot, K. Teinz, E. Kemnitz, Z. Karpinski
  (See online at https://doi.org/10.1016/j.catcom.2012.06.001)
• Nickel fluoro complexes as intermediates in catalytic cross-coupling reactions, J. Fluorine Chem. 2012, 143, 263
  D. Breyer, J. Berger, T. Braun, S. Mebs
  (See online at https://doi.org/10.1016/j.jfluchem.2012.06.025)
• Novel sol-gel prepared zinc fluoride: synthesis, characterisation and the acid-base sites analysis, J. Mater. Chem. 2012, 22, 14587
  Y. Guo, St. Wuttke, A. Vimont, M. Daturi, J.-C. Lavalley, K. Teinz, E. Kemnitz
  (See online at https://doi.org/10.1039/C2JM31357J)
• On the sol-gel synthesis of mag-nesium fluoride and inorganic-organic nanocomposites, Dissertation, Humboldt-Universität zu Berlin, 2011
  Johannes Noack
  
• Palladium-Catalyzed Coupling of Pyrid-4-yl Nonaflates with Methyl Diazoacetate, Synlett 2012, 23(11), 1670
  Ch. Eidamshaus, P. Hommes, H.-U. Reissig
  (See online at https://doi.org/10.1055/s-0031-1290398)
• Platinkomplexe mit fluorierten Phosphanliganden im Supersauren, Dissertation, Freie Universität Berlin, 2012
  Roland Friedemann
  
• Precious metal loaded aluminium hydrixidefluorides as new heterogenous catalysts, Dissertation, Humboldt-Universität zu Berlin, 2012
  Katharina Teinz
  
• Preparation and stabilization of aluminium trifluoroacteate fluoride sols for optical coatings, Dalton Trans. 2012, 41, 11351
  C. Fritz, G. Scholz, M. Feist, E. Kemnitz
  (See online at https://doi.org/10.1039/C2DT31113E)
• Radikalkationen von halogenierten Benzolen und verwandten Aromaten, Dissertation, Freie Universität Berlin, 2012
  Matthias J. Molski
  
• Rhodium-Mediated Synthesis of a Tetrafluoropyridyl-2-boronate Ester, in Efficient Preparations of Fluorine Compounds (Hrsg. Herbert W. Roesky) 2012, 235
  M. Teltewskoi, T. Braun
  (See online at https://doi.org/10.1002/9781118409466.ch34)
• Supramolecular behavior of fluorous polyglycerol dendrons and polyglycerol dendrimers with perfluorinated shells in water, New J. Chem. 2012, 36, 402
  M. Zieringer, M. Wyszogrodzka, K. Biskup, R. Haag
  (See online at https://doi.org/10.1039/C1NJ20741E)
• Synthese und Reaktivität von Iridium(III)fluoridhydridokomplexen: Ansätze zu neuen Fluorie-rungsstrategien, Dissertation, Humboldt-Universität zu Berlin, 2012
  Paul Kläring
  
• Synthesis and Reactivity of the Fluoro Complex trans-[Pd(F)(4-C5NF4)(iPr2PCH2CH2OCH3)2]: C-F Bond Formation and Catalytic C-F Bond Activation Reactions, Organometallics 2012, 31, 1417
  D. Breyer, T. Braun, P. Kläring
  (See online at https://doi.org/10.1021/om200998d)
• Synthesis of Perfluoroalkyl-Substituted γ-Lactones and 4,5-Dihydropyridazin-3(2H)-ones via Donor- Acceptor Cyclopropanes, Helvetica Chimica Acta 2012, 95, 1818
  D. Gladow, H.-U. Reissig
  (See online at https://doi.org/10.1002/hlca.201200413)
• Synthesis of Trifluorostyrene Derivatives by Palladium-Catalyzed Cross-Coupling of Lithium Trimethoxy(trifluorovinyl)borate with Aryl Bromides, Chem. Eur. J. 2012, 18(2), 437
  S. Duric, B. M. Schmidt, N. M. Ninnemann, D. Lentz, C. Ch. Tzschucke
  (See online at https://doi.org/10.1002/chem.201103067)
• Synthesis, Reactivity and Structures of Iridium Tetrafluoropyridyl Complexes: Ammonia Coordination and Activation, Z. Anorg. Chem. 2012, 505
  A.-K. Jungton, P. Kläring, T. Braun, A. Eißler
  (See online at https://doi.org/10.1002/zaac.201100440)
• Synthesis, Structure and Reactivity of Iridium Hydrido Fluorido Complexes, 28, Eur. J. Inorg. Chem. 2012, 1430
  P. Kläring, A.-K. Jungton, T. Braun, C. Müller
  (See online at https://doi.org/10.1002/ejic.201100917)
• Titanium-Catalyzed Vinylic and Allylic C-F Bond Activation - Scope, Limitations and Mechanistic Insight, Chem. Eur. J. 2012, 18(34), 10701
  M. F. Kuehnel, P. Holstein, M. Kliche, J. Krüger, S. Matthies, D. Nitsch, J. Schutt, M. Sparenberg, D. Lentz
  (See online at https://doi.org/10.1002/chem.201201125)
• Trip2C6H3SeF: Das erste isolierte Selenenylfluorid, Angew. Chem. 2012, 124, 433; Trip2C6H3SeF: The First Isolated Selenenyl Fluoride, Angew. Chem. Int. Ed. 2012, 51, 419
  H. Poleschner, S. Ellrodt, M. Malischewski, J. Nakatsuji, Ch. Rohner, K. Seppelt
  (See online at https://doi.org/10.1002/anie.201106708)
• Accommodating fluorinated amino acids in helical peptide environments, RSC Advances 2013, 3(18), 6319
  E. Nyakatura, O. Reimann, T. Vagt, M. Salwiczek, B. Koksch
  (See online at https://doi.org/10.1039/C3RA41110A)
• Alkylation and Ring Opening of Perfluoroalkyl- and Perfluoroalkyl-Substituted 2-Siloxycyclopropanecarboxylates Yielding Fluorinated γ -Oxo Esters or β, γ-Unsaturated Ketones, Synthesis 2013, 45, 2179
  D. Gladow, H.-U. Reissig
  (See online at https://doi.org/10.1055/s-0033-1338892)
• Anion packing, hole filling, and HF solvation in A2(HF)nB12F12 and K2(HF)TiF6 (A = K, Cs), J. Fluorine Chem. 2013, 145, 118
  D. V. Peryshkov, R. Friedemann, E. Goreshnik, Z. Mazej, K. Seppelt, S. H. Strauss
  (See online at https://doi.org/10.1016/j.jfluchem.2012.10.009)
• Catalytic hydrodefluorination of fluoroaromatics with silanes as hydrogen source at a binuclear rhodium complex: Characterization of key intermediates, J. Fluorine Chem. 2013, 155, 132
  L. Zámostná, M. Ahrens, T. Braun
  (See online at https://doi.org/10.1016/j.jfluchem.2013.05.021)
• Catalytic Hydrodefluorination of Fluoromethanes at Room Temperature by Silylium-ion-like Surface Species, Angew. Chem. 2013, 125(20), 5436
  M. Ahrens, G. Scholz, T. Braun, E. Kemnitz
  (See online at https://doi.org/10.1002/anie.201300608)
• Characterising MgF2 surfaces with CO adsorption calculations, Surf. Sci. 2013, 609, 73
  Z. Hüsges, C. Müller28, B. Paulus, Ch. Hough, N. Harrison, E. Kemnitz
  (See online at https://doi.org/10.1016/j.susc.2012.11.004)
• Die schwer fassbaren Halogenide VCl5, MoCl6 und ReCl6, Angew. Chem. 2013, 125, 797; The Elusive Halides VCl5, MoCl6 and ReCl6, Angew. Chem. Int. Ed. 2013, 52, 767
  F. Tamadon, K. Seppelt
  (See online at https://doi.org/10.1002/ange.201207552 https://doi.org/10.1002/anie.201207552)
• Fluorido complexes of Technetium, Dissertation, Freie Universität Berlin, 2013
  Samundeeswari Mariappan Balasekaran
  
• Fluorinated and Trifluoromethylated Buckybowls, Dissertation, Freie Universität Berlin, 2013
  Bernd M. Schmidt
  
• Fluorinated and Trifluoromethylated Corannulenes, Chem. Eur. J. 2013, 19(41), 13872
  B. M. Schmidt, B. Topolinski, M. Yamada, S. Higashibayashi, M. Shionoya, H. Sakurai, D. Lentz
  (See online at https://doi.org/10.1002/chem.201301910)
• Halogenated Benzene Cation Radicals, Eur. J. Org. Chem. 2013, 3131
  M. J. Molski, M. A. Khanfar, H. Shorafa, K. Seppelt
  (See online at https://doi.org/10.1002/ejoc.201201691)
• Hexafluoridotechnetate(IV) Revisited, Inorg. Chem. 2013, 52(12), 7094
  S. M. Balasekaran, M. Molski, J. Spandl, A. Hagenbach, R. Alberto, U. Abram
  (See online at https://doi.org/10.1021/ic400775e)
• Hexafluoridotechnetate(IV), Inorg. Chem. 2013, 52, 7094
  S. M. Balasekaran, M. Molski, J. Spandl, A. Hagenbach, R. Alberto, U. Abram
  (See online at https://doi.org/10.1021/ic400775e)
• Impact of fluorination on proteolytic stability of peptides in human blood plasma, Bioorg. Med. Chem. 2013, 21(12), 3542
  V. Asanté, J. Mortier, H. Schlüter, B. Koksch,
  (See online at https://doi.org/10.1016/j.bmc.2013.03.051)
• Insertion of CS2 into Iridium Fluorine Bonds, Angew. Chem. 2013, 125(42), 11302; Angew. Chem. Int. Ed. 2013, 52(42), 11096
  P. Kläring, T. Braun
  (See online at https://doi.org/10.1002/ange.201305106 https://doi.org/10.1002/anie.201305106)
• Metal Fluoride-Based Transparent Nanocomposites with Low Refractive Index, Dalton Trans. 2013, 42, 5706
  J. Noack, C. Fritz, C. Flügel, F. Hemmann, H.-J. Gläsel, O. Kahle, Ch. Dreyer, M. Bauer, E. Kemnitz
  (See online at https://doi.org/10.1039/C3DT32652G)
• Nitrosylation of Hexafluoridotechnetate (IV), Z. Anorg. Allg. Chem. 2013, 639, 672
  S. M. Balasekaran, M. Molski, A. Hagenbach, U. Abram
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• Reactions of Xenon with Iridiumand Osmiumhexafluoride, Acta Chim. Slov. 2013, 60(3), 491
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• Evaluating Fluorine’s Impact on Amyloid Formation – A Systematic Study Using a Coiled-Coil Based Model Peptide, Dissertation, Freie Universität Berlin, 2014
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• Fluoridonitrosyl Complexes of Technetium(I) and Technetium(II). Synthesis, Characterization, Reactions, and DFT Calculations, Inorg. Chem. 2014, 53(10), 5117
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• Perfluoroalkyl-Substituted Thiophenes and Pyrroles from Donor-Acceptor Cyclopropanes and Heterocumulenes: Synthesis and Exploration of their Reactivity, J. Org. Chem. 2014, 79, 4492
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• Reaktive Rhodium(I)-Silylkom-plexe zur C-F-Aktivierung fluorierter Aromaten und Alkene, Dissertation, Humboldt-Universität zu Berlin, 2014
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• Rotationally adiabatic pair interactions of para- and ortho-hydrogen with the halogen molecules F2, Cl2, and Br2, J. Chem. Phys. 2014, 141, 074303
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• Site-specific incorporation of fluorinated amino acids into basic pancreatic trypsin inhibitor, Dissertation, Freie Universität Berlin, 2014
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• Sol-gel synthesis and characterization of nanoscopi strontium fluoride, RSC Advances 2014, 4, 32
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• Synthese eines Rhodium(I)-Borylkomplexes und dessen Verwendung in C-F-, C-H- und N-H- Akti-vierungs- und Derivatisierungsreaktionen, Dissertation, Humboldt-Universität zu Berlin, 2014
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• Syntheses and Properties of Buckybowls Bearing Electron-withdrawing Groups, Chem. Lett. 2014, 43, 17
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• Synthesis of Cyclopentadiene Ligands with Fluorinated Substituents by Reaction of Cobaltocene with Fluoroalkenes, Eur. J. Inorg. Chem. 2014, 30, 5103
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• Diaryldichalcogenide radical cations, Chem. Sci. 2015, 6, 497
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• Ein durch Halogen-Halogen-Wechselwirkungen zusammengehaltenes 2D-Polychloridnetzwerk, Angew. Chem. 2015, 127, 15800; A 2D Polychloride Network Held Together by Halogen–Halogen Interactions, Angew. Chem. Int. Ed. 2015, 54, 15579
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• Flow Synthesis of Fluorinated α-Amino Acids, Eur. J. Org. Chem. 2015, 14, 3036
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• Fluorine meets peptides, International Innovation 2015, 171, 127
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• Fluorine teams up with water to restore inhibitor activity to mutant BPTI, Chem. Sci. 2015, 6, 5246
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• Fluorreiche Fluoride – neue Erkenntnisse über die Chemie von Polyfluoridanionen, Angew. Chem. 2015, 127(28), 8397; Fluorine Rich Fluorides: New Insights into the Chemistry of Polyfluoride Anions, Angew. Chem. Int. Ed. 2015, 54(28), 8279
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• Formation of nanoscopic CaF2 via a fluorolytic sol-gel process for antireflective coatings, J. Mater. Chem. C 2015, 3, 1716
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• Functionalization of Fluorinated Molecules by Transition-Metal-Mediated C–F Bond Activation To Access Fluorinated Building Blocks, Chem. Rev. 2015, 115(2), 931
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• Jahn–Teller Effect in the B12F12 Radical Anion and Energetic Preference of an Octahedral B6(BF2)6 Cluster Structure over an Icosahedral Structure for the Elusive Neutral B12F12, Inorg. Chem. 2015, 54(23), 11563
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• Nucleophilic Substitution on (Pentafluorophenyl)dipyrromethane: A New Route to Building Blocks for Functionalized BODIPYs and Tetrapyrroles, Org. Lett. 2015, 17, 982
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• Orthogonal translation meets electron transfer: in vivo labeling of cytochrome C for probing local electric fields, Chembiochem 2015, 16, 742
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• Perfluoroalkyl-Functionalized Hyperbranched Polyglycerol as Pore Forming Agents and Supramolecular Hosts in Polymer Microspheres, Int. J. Mol. Sci. 2015, 16(9), 20183
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• Synthesis and Characterization of nano-SrF2 and -YbF3 for Dental Applications, Dissertation, Humboldt-Universität zu Berlin, 2015
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• Synthesis and Functionalization of Fluorinated Tetrapyrroles, Dipyrromethanes and Borondipyrrins, Dissertation, Freie Universität Berlin, 2015
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• Synthesis and structure of rhodium(I) silyl carbonyl complexes: photochemical C-F and C-H bond activation of fluorinated aromatic compounds, Dalton Trans. 2015, 44, 9450
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• The effect of electron correlation on the adsorption of hydrogen fluoride and water on magnesium fluoride surfaces, Phys. Chem. Chem. Phys. 2015, 17, 18722
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• Adaptation of E. coli towards Tryptophan analogue usage, Dissertation, Technische Universität Berlin, 2016
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• Biocompatible fluorinated polyglycerols for droplet microfluidics as an alternative to PEG-based copolymer surfactants, Lab Chip 2016, 16, 65
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• C-F-Bindungsaktivierung in Gegenwart von Metallocenen der Gruppe 3 und 4, Dissertation, Freie Universität Berlin, 2016
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• Calculation of Zn, Cd, Hg adsorption on graphene with incremental CCSD(T) and range-separated hybrid DFT*, Mol. Phys. 2016, 114(7-8), 1098
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• Competing reaction pathways of 3,3,3-trifluoropropene at rhodium hydrido, silyl and germyl complexes: C-F bond activation versus hydrogermylation, Dalton Trans. 2016, 45, 17495
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• Competition of Nucleophilic Aromatic Substitution, σ‐Bond Metathesis, and syn Hydrometalation in Titanium(III)‐Catalyzed Hydrodefluorination of Arenes, Chem. Asian J. 2016, 11(21), 3062
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• Coordination chemistry and oxidative addition of trifluorovinylferrocene derivatives, J. Fluorine Chem. 2016, 192, 105
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• Effects of Chloride Additives on Mechanical Stability and Environmental Durability of Porous MgF2 Thin Films, Proc. of SPIE 2016, 9929, 992914-1-7
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• Elektrophile Fluorierungsreaktionen an Palladium- und Platin-Alkinkomplexen, Dissertation, Humboldt-Universität zu Berlin, 2016
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• Fluorine in fragrances: exploring the difluoromethylene (CF2) group as a conformationalconstraint in macrocyclic musk lactones, Organic & Biomolecular Chemistry 2016, 14, 211
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• Formation of nanoscopic calcium fluoride via sol-gel synthesis, Dissertation, Humboldt-Universität zu Berlin, 2016
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• From surface properties towards a multiscale approach for modelling MgF2 nanocrystals, Dissertation, Freie Universität Berlin, 2016
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• Heterogeneous Catalytic Hydroarylation of Olefins at a Nanoscopic Aluminum Chlorofluoride, ChemCatChem 2016, 8, 1945
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• How a Thermally Unstable Metal Hydrido Complex Can Yield High Catalytic Activity Even at Elevated Temperatures, Chem. Eur. J. 2016, 22(27), 9305
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• Improved parameterization of the quantum harmonic oscillator model based on localized wannier functions to describe Van der Waals interactions in density functional theory, Int. J. Quant. Chem. 2016, 116(15), 1160
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• Improving selectivity in catalytic hydrodefluorination by limiting SNV reactivity, Dalton Trans. 2016, 45, 16789
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• Isolation and structural and electronic characterization of salts of the decamethylferrocene dication, Science 2016, 353, 678
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• Klick-Reaktionen an der Arsen-Kohlenstoff-Dreifachbindung: Zugang zu einer neuen Klasse arsenhaltiger Heterocyclen, Angew. Chem. 2016, 128, 1
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• Komplexe zyklischer π-Perimeter mit fluorierten Substituenten, Dissertation, Freie Universität Berlin, 2016
  Darina Heinrich
  
• Local Structures of Solid Solutions Sr1-xYxF2+x with Fluorite Structure Prepared by Sol-Gel and Mechanochemical Syntheses, J. Phys. Chem. C 2016, 120, 8992
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• Mechanochemical synthesis, structure, and properties of solid solutions of alkaline earth metal fluorides: Ma(1-x)Mb(x)F2 (M: Ca, Sr, Ba), Solid State Sciences 2016, 60, 65
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• Molecular Receptors Based on Bridged Corannulenes, Dissertation, Freie Universität Berlin, 2016
  Annika Kristin Meyer
  
• Octafluoridodirhenate(III) revisited: Solid-state preparation, characterization and multi-configurational quantum chemical calculations, Inorg. Chem. 2016, 55, 96
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• Perfluoroalkylated Linear Polyglycerols as Nonionic Surfactant for Micellar and Vesicular Carriers, Polym. Chem. 2016, 7, 2222
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• Reaktionen perfluorierter und permethylierter Verbindungen mit starken Oxidationsmitteln, Dissertation, Freie Universität Berlin, 2016
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• Structures of M2(SO2)6B12F12 (M = Ag or K) and Ag2(H2O)4B12F12: Comparison of the Coordination of SO2 versus H2O and of B12F122– versus Other Weakly Coordinating Anions to Metal Ions in the Solid State,Inorg. Chem. 2016, 55(23) 12254
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• Synthese fluorierter 1,10-Phenanthrolin-Derivate und Erfassung der biologischen Aktivität ihrer Kupfer(II)-Komplexe, Dissertation, Freie Universität Berlin, 2016
  Carsten Lüdtke
  
• [NMe4][I4Br5]: A new Iodobromide from an Ionic Liquid with Halogen-Halogen Interactions, Chem. Eur. J. 2017, 23, 244
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• [TcII(NO)(trifluoroacetate)4F]2 - – synthesis and reactions, Dalton Trans. 2017, 46, 13544
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• Activation of CS2 and COS at a Rhodium(I) Germyl Complex: Generation of CS and Carbido Complexes, J. Inorg. Chem. 2017, 3, 713
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• An expanded genetic code for probing the role of electrostatics in enzyme catalysis by vibrational Stark spectroscopy, Biochim. Biophys. Acta 2017, 1861, 3053
  J. S. Völler, H. Biava, P. Hildebrandt, N. Budisa
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• Consecutive Transformations of Tetrafluoropropenes: Hydrogermylation and Catalytic C−F Activation Steps at a Lewis Acidic Aluminum Fluoride, Angew. Chem. 2017, 129, 16556; Angew. Chem. Int. Ed. 2017, 56, 16338
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• Core-shell metal fluoride nanoparticles via fluorolytic sol-gel synthesis – a fast and efficient construction kit, J. Mater. Chem. C 2017, 5, 5444
  B. Ritter, P. Haida, T. Krahl, G. Scholz, E. Kemnitz
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• Coupling genetic code expansion and metabolic engineering for synthetic cells, Curr. Opin. Biotech. 2017, 48, 1
  J. S. Völler, N. Budisa
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• Crystal Structure Determination of the Pentagonal‐Pyramidal Hexamethylbenzene Dication C6(CH3)62+, Angew. Chem. Int. Ed. 2017, 56, 368; Angew. Chem. 2017, 129, 374
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• Deciphering the Fluorine Code – The Many Hats Fluorine Wears in a Protein Environment, Acc. Chem. Res. 2017, 50(9), 2093
  A. A. Berger, J.-S. Völler, N. Budisa, B. Koksch
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• Discovery and investigations of editing function of natural AARSs against synthetic perfluorinated amino acids in protein translation, ACS Central Science 2017, 3(1), 73
  J. Völler, M. Dulic, U. Gerling-Driessen, H. Biava, T. Baumann, N. Budisa, I. Gruic-Sovuli, B. Koksch
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• Et3GeH versus Et3SiH: Controlling Reaction Pathways in Catalytic C-F bond Activations at a Nanoscopic Aluminium Chlorofluoride, Catal. Sci. Technol. 2017, 7, 3348
  G. Meißner, D. Dirican, C. Jäger, T. Braun, E. Kemnitz
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• Global substitution of hemeproteins with noncanonical amino acids in Escherichia coli with intact cofactor maturation machinery, Enzyme and Microbial Technology 2017, 106, 55
  J.-S. Völler, T. M. T. To, H. Biava, B. Koksch, N. Budisa
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• Hypervalente Iodverbindungen in den Oxidationsstufen +III und +V, Dissertation, Freie Universität Berlin, 2017
  Stefan Ellrodt
  
• Isolation and Characterization of a Non‐Rigid Hexamethylbenzene–SO2+ Complex, Angew. Chem. Int. Ed. 2017, 56, 16495; Angew. Chem. 2017, 129, 16718
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• Künstliche Evolution des genetischen Codes von Mikroorganismen, BIOspektrum 2017, 23, 146
  J. S. Völler, M. G. Hoesl, N. Budisa
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• Mechanochemical synthesis of PbF2 by high energy ball milling, Solid State Sci., 2017, 72, 41
  M. Heise, G. Scholz, E. Kemnitz
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• New Trifluoromethyl-Substituted Heterocycles by Multicomponent Reactions of Siloxycyclopropanes, Chem. Heterocycl. Compd. 2017, 53, 416
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• Novel and easy access to highly luminescent Eu and Tb doped ultra-small CaF2, SrF2 and BaF2 nanoparticles - structure and luminescence, Dalton Trans. 2017, 46(9) 2925
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• Novel Superacids: Formation of Pentafluoroorthotellurate Derivatives of Aluminium, Angew. Chem. Int. Ed. 2017, 56, 8263; Supersäuren basierend auf Pentafluoroorthotelluraten des Aluminiums, Angew. Chem. 2017, 129(28), 8375
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• On the Morphology of Group II Metal Fluoride Nanocrystals at Finite Temperature and Partial Pressure of HF, Molecules 2017, 22, 663
  Z. Kaawar, S. Mahn, E. Kemnitz, B. Paulus
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• Position-dependent impact of hexafluoroleucine and trifluoroisoleucine on protease digestion, Beilstein J. Org. Chem. 2017, 13, 2869
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• Protonation of Ferrocene: A Low‐Temperature X‐ray Diffraction Study of [Cp2FeH](PF6) Reveals an Iron‐Bound Hydrido Ligand, Angew. Chem. Int. Ed. 2017, 56, 13372; Angew. Chem. 2017, 129, 13557
  M. Malischewski, K. Seppelt, J. Sutter, F. W. Heinemann, B. Dittrich, K. Meyer
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• Selecive Reduction of a C-Cl Bond in Halomethanes with Et3GeH at Nanoscopic Lewis Acidic Aluminium Fluoride, J. Organomet. Chem. 2017, 847, 234
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• Solid state structures of fluorine-rich fluoranthenes, CrystEngComm 2017, 19, 1328
  B. M. Schmidt, A. K. Meyer, D. Lentz
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• Sol–gel synthesis of Sr1-xYbxF2+x nanoparticles dispersible in acrylates, RSC Advances 2017, 7, 56266
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• Synthesis of Fluorinated Amino Acids and Their Derivatives in Flow, Dissertation, Freie Universität Berlin, 2017
  Stella Vukelic
  
• Synthesis of fluorine-containing 1,10-phenanthrolines using mild versions of Skraup and Doebnervon Miller reactions, J. Fluorine Chem. 2017, 193, 98
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• Taming the High Reactivity of Gold(III) Fluoride: Fluorido Gold(III) Complexes with N-Based Ligands, Chem. Eur. J. 2017, 23, 13501
  M. A. Ellwanger, S. Steinhauer, P. Golz, H. Beckers, A. Wiesner, B. Braun-Cula, T. Braun, S. Riedel
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• The Multiple Origins of the Hydrophobicity of Tri- and Hexa-Fluorinated polar Amino Acids, Chem. (Cell Press) 2017, 3(5), 881
  J. R. Robalo, S. Huhmann, B. Koksch, A. Vila Verde
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• The Reaction of Cs2[Tc(NO)F5] with BF3 in Acetonitrile: Formation and Structure of [{Tc(NO)(CH3CN)4}2(μ-F)](BF4)3, Z. Anorg. Allg. Chem. 2017, 643, 1146
  S. M. Balasekaran, A. Hagenbach, J. Spandl, U. Abram
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• The Versatile Behavior of Platinum Alkyne Complexes towards XeF2: Formation of Fluorovinyl and Fluorido Complexes, B. Braun-Culam Chem. Eur. J. 2017, 23, 8886
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• Theoretical investigation of the crystal structure of AlOF, Chem. Phys. 2017, 491, 112
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• Theoretical investigations of the CO adsorption on ZnF2 surfaces, Surf. Sci. 2017, 656, 48
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• Theoretical investigations of weak interactions in fluorine containing compounds, Dissertation, Freie Universität Berlin, 2017
  Matthias Berg
  
• Triazaphospholenium Tetrafluoroborate: A Phosphorus Analogue of a 1,2,3-Triazole-Derived Carbene, Angew. Chem. Int. Ed. 2017, 56, 16484; Triazaphospholenium-tetrafluoroborat: das Phosphoranalogon eines von 1,2,3- Triazol abgeleiteten Carbens, Angew. Chem. 2017, 129, 16706
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• Verwendung eines reaktiven Rhodium(I)-Germylkomplexes in C–F-, C–H- und C-S Bindungsaktivierungsreaktionen, Dissertation, Humboldt-Universität zu Berlin, 2017
  Theresia Ahrens
  
• Xenobiology meets enzymology: Exploring the potential of unnatural building blocks in biocatalysis, Angew. Chem. Int. Ed. 2017, 56(33), 9680
  F. Agostini, J.-S. Völler, B. Koksch, C.G. Acevedo-Rocha, V. Kubyshkin, N. Budisa
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• [P4H]+[Al(OTeF5)4]-: Protonation of White Phosphorus with the Brønsted Superacid H[Al(OTeF5)4](solv), Chem. Sci. 2018, 9, 7169
  A. Wiesner, S. Steinhauer, H. Beckers, Ch. Müller, S. Riedel
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• A Computational Study of AlF3 and ACF Surfaces, Inorganics 2018, 6, 124
  R. Pandharkar, C. Becker, J. H. Budau, Z. Kaawar, B. Paulus
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• A Ferrocene‐Based Dicationic Iron(IV) Carbonyl Complex, Angew. Chem. Int. Ed. 2018, 57, 14597; Angew. Chem. 2018, 130, 14806
  M. Malischewski, K. Seppelt, J. Sutter, D. Munz, K. Meyer
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• Activation of SF6 at a Xantphos-Type Rhodium Complex, Organometallics 2018, 37, 821
  M. Wozniak, T. Braun, M. Ahrens, B. Braun- Cula, P. Wittwer, R. Herrmann, R. Laubenstein
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• Aluminum oxo-fluoride clusters: A first principle investigation of stability, synthetic considerations, and the interaction with water, J. Comput. Chem. 2018, 39(19), 1208
  J. Schacht, J. H. Budau, N. Gaston, B. Paulus
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• Comparative Study of the Strongest Lewis Acids Known: ACF and HS-AlF3, Dalton Trans. 2018, 47, 16461
  B. Calvo, C. P. Marshall, T. Krahl, J. Kröhnert, A. Trunschke, G. Scholz, T. Braun, E. Kemnitz
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• Darstellung von Corannulenen mit stark elektronenziehenden Substituenten und Untersuchung ihrer strukturellen, dynamischen sowie elektrochemischen Eigenschaften, Dissertation, Freie Universität Berlin, 2018
  Axel Haupt
  (See online at https://doi.org/10.17169/refubium-17971)
• Development of complex magnesium fluoroaluminates via the fluorolytic sol–gel synthesis, J. Mater. Chem. C 2018, 6, 72
  F. Schütz, M. Bäthge, K. Scheurell, G. Scholz, M. Feist, E. Kemnitz
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• Efficient Artificial Nucleases for Mediating DNA Cleavage Based on Tuning the Steric Effect in the Pyridyl Derivatives of Tripod Tetraamine-cobalt(II) Complexes, Eur. J. Inorg. Chem., 2018, 2322
  S. Doniz Kettenmann, F. R. Louka, E. Marine, R. C. Fischer, F. A. Mautner, N. Kulak, S. S. Massoud
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• Fine-tuning the proteolytic stability of peptides with fluorinated amino acids, Eur. J. Org. Chem. 2018, 3667
  S. Huhmann, B. Koksch
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• First-principles investigation of fluoride doping in bulk and on surfaces of aluminium (oxo)hydroxides, Dissertation, Freie Universität Berlin, 2018
  Johannes Horst Budau
  (See online at https://doi.org/10.17169/refubium-428)
• From enzymatic in vitro and in vivo synthesis of fluorinated amino acids to fluorine-based bacteria, Dissertation, Freie Universität Berlin, 2018
  Federica Agostini
  
• Further Development of Weakly Coordinating Cations: Fluorinated Bis(triarylphosphoranylidene)iminium Salts, Chem. Eur. J. 2018, 24(15), 3902
  L. Mann, E. Hornberger, S. Steinhauer, S. Riedel
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• Gallium Hydrides and O/N‐Donors as Tunable Systems in C−F Bond Activation, Chem. Asian J. 2018, 13, 2908
  A. D. Jaeger, R. Walter, Ch. Ehm, D. Lentz
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• Hydrogen/Deuterium-Exchange Reactions of Methane with Aromatics and Cyclohexane Catalyzed by a Nanoscopic Aluminium Chlorofluoride, ChemCatChem 2018, 10, 403
  B. Calvo, T. Braun, E. Kemnitz
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• Investigation of Organonickel‐Pentafluoroorthotellurates, Z. Anorg. Allg. Chem. 2018, 644(17), 1047
  S. Hämmerling, L. Mann, S. Steinhauer, M. W. Kuntze‐Fechner, U. Radius, S. Riedel
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• Investigation of Polybromides, Non-Classical Polyinterhalides Based on ICl and IBr, and Fluorinated [PPN]+-Salts, Dissertation, Freie Universität Berlin, 2018
  Lisa Mann
  
• Long-Range Modulations of Electric Fields in Proteins, J. Phys. Chem. B 2018, 122, 8330
  H. Biava, T. Schreiber, S. Katz, J. S. Völler, M. Stolarski, C. Schulz, N. Michael, N. Budisa, J. Kozuch, T. Utesch, P. Hildebrandt
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• Mechanochemical synthesis, structure and properties of lead containing alkaline earth metal fluoride solid solutions MxPb1-xF2 (M = Ca, Sr, Ba), Solid State Sci. 2018, 77, 45
  M. Heise, G. Scholz, A. Düvel, P. Heitjans, E. Kemnitz
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• Methylselenium Triiodide, [CH3SeI2]+I–, Z. Anorg. Allg. Chem. 2018, 644, 1492
  B. Müller, S. Ellrodt, K. Seppelt
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• Mussel-Inspired Polyglycerols as Surface Coatings with Controllable Wettability, Dissertation, Freie Universität Berlin, 2018
  Christoph Schlaich
  (See online at https://doi.org/10.17169/refubium-5749)
• Organo- und seltenerdmetallkatalysierte C-F-Bindungsaktivierung mit Hilfe von Aluminium- und Galliumhydriden, Dissertation, Freie Universität Berlin, 2018
  Alma Dorothea Jaeger,
  (See online at https://doi.org/10.17169/refubium-1292)
• Organocatalytic C@F Bond Activation with Alanes, Chem. Eur. J. 2018, 24, 6769
  A. D. Jaeger, Ch. Ehm, D. Lentz
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• Polybromide Dianions and Networks Stabilized by Fluorinated Bromo(triaryl)phosphonium Cations, Eur. J. Inorg. Chem. 2018, 28, 3330
  L. Mann, G. Senges, K. Sonnenberg, H. Haller, S. Riedel
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• Rare Earth Metal Catalyzed C–F Bond Activation, Z. Anorg. Allg. Chem. 2018, 644(21), 1229
  A. D. Jaeger, D. Lentz
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• Reactions of [ReOCl3(PPh3)2] with 4-fluoroaniline, Z. Anorg. Allg. Chem. 2018, 644, 1451
  C. Scholtysik, M. Roca Jungfer, A. Hagenbach, U. Abram
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• Reactions of [ReOCl3(PPh3)2] with 4‐Fluoroaniline, Z. Allg. Anorg. Chem. 2018, 644(22), 1451
  C. Scholtysik, M. Roca Jungfer, A. Hagenbach, U. Abram
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• Reactivity of 3,3,3-Trifluoropropyne at Rhodium Complexes: Development of Hydroboration Reactions, Chem. Eur. J. 2018, 24, 11131
  C. von Hahmann, M. Talavera, C. Xu, T. Braun
  (See online at https://doi.org/10.1002/chem.201801662)
• Reactivity of Rhodium and Iridium Peroxido Complexes towards Hydrogen in the Presence of B(C6F5)3 or [H(OEt2)2][B{3,5 (CF3)2C6H3}4], Dalton Transactions 2018, 47, 16299
  H. Baumgarth, G. Meier, C. N. von Hahmann, T. Braun
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• Reactivity of Rhodium Hydrido and Silyl Complexes Towards 1,1-Difluoroallene, J. Fluorine Chem. 2018, 214, 80
  A. L. Raza, M. F. Kuehnel, M. Talavera, M. Teltewskoi, M. Ahrens, P. Kläring, T. Braun, D. Lentz
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• Rhenium- und Technetiumphenylimidokomplexe mit fluorierten Liganden, Dissertation, Freie Universität Berlin, 2018
  Clemens Scholtysik
  (See online at https://doi.org/10.17169/refubium-12653)
• Salts of the Weakly Coordinating Anion [Al(OTeF5)4]– containing Reactive Counterions, Z. Anorg. Allg. Chem. 2018, 644(21), 1344
  K. F. Hoffmann, A. Wiesner, N. Subat, S. Steinhauer, S. Riedel
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• Selective Synthesis of Perfluoroalkylated Corannulenes and Investigation of their Structural, Dynamic and Electrochemical Behavior, Chem. Eur. J. 2018, 24(42), 10756
  A. Haupt, L.-M. Keller, M. Kutter, D. Lentz
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• Selectivity of C–H Activation and Competition between C–H and C–F Bond Activation at Fluorocarbons, Eur. J. Inorg. Chem. 2018, 117(13), 4031
  H. Schneider, A. Hock, A. D. Jaeger, D. Lentz, U. Radius
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• Stabilization of Lewis Acidic AuF3 as an N-Heterocyclic Carbene Complex: Preparation and Characterization of [AuF3 (SIMes)], Angew. Chem. Int. Ed. 2018, 57, 7210
  M. Ellwanger, S. Steinhauer, P. Golz, T. Braun, S. Riedel
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• Stabilization of Lewis Acidic AuF3 as Carbene Complex: Preparation and Characterization of [AuF3(SIMes)], Angew. Chem. Int. Ed. 2018, 57, 7210; Angew. Chem. 2018, 130, 7328
  M. A. Ellwanger, S. Steinhauer, P. Golz, T. Braun, S. Riedel
  (See online at https://doi.org/10.1002/anie.201802952 https://doi.org/10.1002/ange.201802952)
• Stabilization of peptides by site-specific incorporation of fluorinated amino acids: Model studies and the development of fluorinated, peptide-based HIV-1 fusion inhibitors, Dissertation, Freie Universität Berlin, 2018
  Susanne Huhmann
  (See online at https://doi.org/10.17169/refubium-1455)
• Structure of (SiEt3)2(B12F12). Another example of R3SiFE bridge bonding (E = B, Al, Si), J. Fluor. Chem. 2018, 212, 107
  M. Malischewski, E. V. Bukovsky, S. H. Strauss, K. Seppelt
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• Synthesis and Characterization of Perovskite-Type [K1-xNax]MgF3 Mixed Phases via the Fluorolytic Sol- Gel Synthesis, Crystals 2018, 8, 66
  F. Schütz, L. Lange, K. Scheurell, G. Scholz, E. Kemnitz
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• Tetracyanocorannulene – an Easily Accessible and Strongly Electron-Deficient Compound, Eur. J. Org. Chem. 2018, 6338
  A. Haupt, R. Walter, B. Loll, D. Lentz
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• Tetrafluoridonitridotechnetate(VI) – Reactions and Structures, Z. Anorg. Allg. Chem. 2018, 644, 1158
  S. M. Balaskaran, A. Hagenbach, U. Abram
  (See online at https://doi.org/10.1002/zaac.201800206)
• Theoretical investigation of bulk and surface properties of group II and group XII metal fluorides, Dissertation, Freie Universität Berlin, 2018
  Zeinab Kaawar
  (See online at https://doi.org/10.17169/refubium-11)
• Thiosemicarbazones and thiadiazines derived from fluorinated benzoylthioureas: synthesis, crystal structure and anti-Trypanosoma cruzi activity, J. Fluorine Chem. 2018, 215, 52
  F. Salsi, G. Bulhões Portapilla, K. Schutjajew, Z. Aparecida Carneiro, A. Hagenbach, S. de Albuquerque, U. Abram
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• Tuning the Electron Affinity and Stacking Properties of Corannulene by Introduction of Fluorinated Thioethers, Chem. Asian J. 2018, 13, 3022
  A. Haupt, D. Lentz
  (See online at https://doi.org/10.1002/asia.201801311)
• Tuning the Lewis Acidity of Difluorido Gold(III) Complexes: Synthesis of [AuClF2(SIMes)] and [AuF2(OTeF5)(SIMes)], Chem. Comm. 2018, 54, 9301
  M. A. Ellwanger, C. von Randow, S. Steinhauer, Y. Zhou, A. Wiesner, H. Beckers, T. Braun, S. Riedel
  (See online at https://doi.org/10.1039/c8cc05233f)
• Uranium and Thorium Complexes with Aroylbis(N,N-dialkylthioureas), Dissertation, Freie Universität Berlin, 2018
  Christelle Njiki Noufele
  (See online at https://doi.org/10.17169/refubium-16291)
• Biological activity of amphiphilic metal complexes, Coord. Chem. Rev. 2019, 385, 191
  C. Schattschneider, S. Doniz Kettenmann, S. Hinojosa, J. Heinrich, N. Kulak
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• Corannulenes with Electron-Withdrawing Substituents – Synthetic Approaches and Resulting Structural and Electronic Properties, Chem. Eur. J. 2019, 25, 3440
  A. Haupt, D. Lentz
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• No Fear of Perfluorinated Peroxides: Syntheses and Solid‐State Structures of Surprisingly Inert Perfluoroalkyl Peroxides, Angew. Chem. Int. Ed. 2019, 58, 3584; Angew. Chem. 2019, 131, 3622
  J. H. Nissen, T. Stüker, Th. Drews, S. Steinhauer, H. Beckers, S. Riedel
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• The Crystal Structure of α‐F2: Solving a 50 Year Old Puzzle Computationally, Chem. Eur. J. 2019, 25(13), 3318
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