Alpha-Azido Alcohols and Other Short Lived Azides

• Applicant: Professor Dr. Klaus Banert (†)
• Subject Area: Organic Molecular Chemistry - Synthesis and Characterisation
• Term: from 2008 to 2017
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 81098143

• Final Report Year: 2017

Final Report Abstract

No abstract available

Publications

• Reactions of Unsaturated Azides, Part 29. Experimental and Theoretical Studies on the Synthesis, Spectroscopic Data, and Reactions of Formyl Azide, Angew. Chem. 2012, 124, 4796–4800; Angew. Chem. Int. Ed. 2012, 51, 4718–4721
  K. Banert, C. Berndt, M. Hagedorn, H. Liu, T. Anacker, J. Friedrich, G. Rauhut
  
• Extremely Simple but Long Overlooked: Generation of α-Azido Alcohols by Hydroazidation of Aldehydes, Angew. Chem. 2010, 122, 10404–10407; Angew. Chem. Int. Ed. 2010, 49, 10206–10209
  K. Banert, C. Berndt, S. Firdous, M. Hagedorn, Y.-H. Joo, T. Rüffer, H. Lang
  
• Reactions of Unsaturated Azides, Part 30. 1-Azido-1-alkynes: Synthesis and Spectroscopic Characterization of Azidoacetylene, Angew. Chem. Int. Ed. 2012, 51, 7515–7518
  K. Banert, R. Arnold, M. Hagedorn, P. Thoss, A. A. Auer
  
• Azidoacetylene – interpretation of gas phase infrared spectra based on high-level vibrational configuration interaction calculations, Phys. Chem. Chem. Phys. 2013, 15, 6719–6725
  D. Oschetzki, X. Zeng, H. Beckers, K. Banert, G. Rauhut
  
• Formyl Azide: Properties and Solid-State Structure, Angew. Chem. 2013, 125, 3587–3591; Angew. Chem. Int. Ed. 2013, 52, 3503–3506
  X. Zeng, E. Bernhardt, H. Beckers, K. Banert, M. Hagedorn, H. Liu
  
• Reactions of Unsaturated Azides, Part 32. Well Known or New? Synthesis and Structure Assignment of Binary C2N14 Compounds Reinvestigated, Angew. Chem. 2013, 125, 3583–3586; Angew. Chem. Int. Ed. 2013, 52, 3499–3502
  K. Banert, S. Richter, D. Schaarschmidt, H. Lang
  
• The Photochemical and Thermal Decomposition of Azidoacetylene in the Gas Phase, Solid Matrix, and Solutions, Eur. J. Org. Chem. 2014, 4077–4082
  X. Zeng, H. Beckers, J. Seifert, K. Banert
  
• Reactions of Unsaturated Azides, Part 34. Rearrangement Reactions of Tritylcarbenes: Surprising Ring Expansion and Computational Investigation, Chem. Eur. J. 2015, 21, 14911–14923
  K. Banert, M. Hagedorn, T. Pester, N. Siebert, C. Staude, I. Tchernook, K. Rathmann, O. Hollóczki, J. Friedrich
  
• Synthesis, Characterization and Reactions of (Azidoethynyl)trimethylsilane, Molecules 2015, 20, 21328–21335
  K. Banert, M. Hagedorn, Z. Wu, X. Zeng
  
• The Chemistry of Unusually Functionalized Azides (Review), Synthesis 2016, 48, 2361–2375
  K. Banert
  
• Direct observation and characterisation of 3-azido-2H-azirines: postulated, but highly elusive intermediates, Org. Chem. Front. 2017, 4, 191−195
  K. Weigand, N. Singh, M. Hagedorn, K. Banert
  
• Synthesis of Geminal Azido−Halo Compounds and α-Azidoalkyl Esters from Aldehydes via α-Azido Alcohols, Org. Lett. 2017, 19, 4900−4903
  K. Banert, C. Berndt, K. Weigand