Neuartige nichtklassische Phosphor-Hybridliganden: Synthese und Koordinationsverhalten 2-funktionell substituierter und anellierter Azaphosphole als Hybridliganden mit Pi-acidem niederkoordiniertem Phosphor und klassischem O- oder N-Donorzentrum

• Applicant: Professor Dr. Joachim Heinicke
• Subject Area: Inorganic Molecular Chemistry - Synthesis and Characterisation
• Term: from 2004 to 2009
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 5441611

• Final Report Year: 2009

Final Report Abstract

No abstract available

Publications

• "Low-Coordinate Group 15/14 Elements In Heterocycles Related To Anellated Imidazoles", Proceedings of the 10th International Symposium on Natural Product Chemistry 06.-09. January 2006 in Karachi
  J. Heinicke
  
• " 1,2-Dibromoethan - A Versatile Reagent in Organic Synthesis (Synlett Spotlight 242)", Synlett, 2008, 1579-1580
  B. Reddy Aluri
  
• "2-Hydroxy- and 2-Amino-functional Arylphosphines - Syntheses, Reactivity and Use in Catalysis", Phosphorus, Sulfur, and Silicon 2008, 183 (02-03), 224-232
  J. Heinicke, W. Wawrzyniak, N. Peulecke, B. R. Aluri, M. K. Kindermann, P.G. Jones, S. Enthaler, M. Beller
  
• "3-Amino- and 3-acylamido-2-phosphonopyridines: Synthesis by Pd-catalyzed P-C coupling, structure and conversion to pyrido[b]-anellated P=C-N heterocycles", Tetrahedron, 2008, 64, 7960-7967; Synfacts 2008, 10, 1025-1025
  M. S. S. Adam, O. Kühl, M. K. Kindermann, J. W. Heinicke, P. G. Jones
  
• "Bulky N-Substituted 1,3-Benzazaphospholes: Access via Pd-Catalyzed C-N and C-P Cross Coupling, Lithiation and Conversion to Novel P=C-PtBu2 Hybrid Ligands", Inorg. Chem., 2008, 47, 6900-6912
  B. R. Aluri, M. K. Kindermann, P. G. Jones, I. Dix, J. W. Heinicke
  
• "Novel Benzo-and Pyrido-Anellated 1, 3-Azaphospholes", Phosphorus, Sulfur, and Silicon 2008, 183 (02-03), 779-782
  J. Heinicke, B. R. Aluri, M. S. S. Adam, P.G. Jones
  
• "Sterically and polarity-controlled reaction of tBuLi with -P=CH-NR-heterocycles: Novel heterocyclic P- and P,O-ligands and preliminary tests in transition metal catalysis", Chem. Eur. J., 2008, 14, 4328- 4335
  B. R. Aluri, M. K. Kindermann, P. G. Jones, J. W. Heinicke