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Complex mercury-based compounds

Subject Area Physical Chemistry of Solids and Surfaces, Material Characterisation
Experimental Condensed Matter Physics
Solid State and Surface Chemistry, Material Synthesis
Term since 2023
Project identifier Deutsche Forschungsgemeinschaft (DFG) - Project number 528628333
 
The proposed project is aimed at the synthesis and characterization of crystallographically complex solid-state compounds, containing rare-earth elements and mercury. So far, a comprehensive study of these compounds has not been possible, due to their extreme air- and moisture-sensitivity. By implementing several novel experimental techniques, we are now able to thoroughly characterize these materials. According to our preliminary work, these systems exhibit peculiar properties – both from physics and chemistry points of view. Their ground states are diverse, which is likely a result of their distinct bonding features. To understand the underlying mechanisms, responsible for superconductivity and magnetism in these compounds, we propose to implement a comprehensive study across the rare-earth series. The results will contribute to the deeper understanding of solid-state chemistry and condensed matter physics of rare-earth-based compounds. This work will also serve the advancement of new routes in the search for materials with exotic ground state properties.
DFG Programme Research Grants
 
 

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