Project Details
Projekt
Totalsynthese natürlicher und unnatürlicher Carotinoid-Butenolide: Peridinin, Pyrrhoxanthin und Modellchromophore des Lichtsammel-Chromoproteins aus Amphidinium carterae
Applicant
Professor Dr. Reinhard Brückner
Subject Area
Organic Molecular Chemistry - Synthesis and Characterisation
Term
from 2000 to 2008
Project identifier
Deutsche Forschungsgemeinschaft (DFG) - Project number 5284654
Final Report Year
2009
Final Report Abstract
No abstract available
Publications
- „Stereoselective Preparation of (E)-a-Bromoacrylates from Mixtures of Brominated Ando Phosphonates“. Synthesis 2004, 2135-2152
T. Olpp, R. Brückner
- „Eine neue Strategie für die Synthese des Butenolid-Teils von Peridinin“. Angew. Chem. 2005, 117, 1577-1581; Angew. Chem. Int. Ed. 2005, 44, 1553- 1557
T. Olpp, R. Brückner
- „Synthesis of the 2-Alkenyl-4-alkylidenebut-2-eno-4-lactone (= a-Alkenyl-g-alkylidenebutenolide) Core Structure of the Carotenoid Pyrrhoxanthin via the Regioselective Dihydroxylation of Hepta-2,4-diene-5-ynoic Acid Esters“. Helv. Chim. Acta 2005, 88, 1943-1959
J. Schmidt-Leithoff, R. Brückner
- „The Stille Reaction in the Synthesis of Carotenoid Butenolides: Synthesis of 6’-epi-Peridinin“. Org. Lett. 2005, 7, 545-548
B. Vaz, R. Alvarez, R. Brückner, A. R. de Lera
- „Regioselective Cis-vic-Dihydroxylation of a,b,g,d-Unsaturated Carboxylic Esters: Enhanced g,d-Selectivity by Employing Trifluoroethyl or Hexafluoroisopropyl Esters“. Synlett 2006, 2641-2645
J. Schmidt-Leithoff, R. Brückner
- „Totalsynthese des lichtsammelnden Carotinoids Peridinin“. Angew. Chem. 2006, 118, 4128-4132; Angew. Chem. Int. Ed. 2006, 45, 4023-4027
T. Olpp, R. Brückner
- „Totalsynthese von natürlich konfiguriertem Pyrrhoxanthin, einem Carotinoid-Butenolid aus Plankton”. Angew. Chem. 2008, 120, 7777-7782; Angew. Chem. Int. Ed. 2008, 47, 7664-7668
J. Burghart, R. Brückner
- „Stereocomplementary Syntheses of 1,w-Distannylated E,Z-Isomeric Conjugated Trienes, Tetraenes, and Pentaenes”. Chem. Eur. J.
J. Burghart, A. Sorg, R. Brückner
