Combinatorial exploration of thermochromic thin films in V-M1-M2-O systems

• Applicant: Professor Dr.-Ing. Alfred Ludwig
• Subject Area: Synthesis and Properties of Functional Materials
• Term: since 2021
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 463914389

This project addresses the exploration of VO2-based thermochromic thin films in V-M1-M2-O systems (M1, M2: e.g. W, Mg, Er, Li) for future application in smart windows. Films to be developed will show high luminous transmittance (Tlum) and solar irradiation modulation (ΔTsol) upon a reversible phase transformation around room temperature. Addition of third elements can decrease the transition temperature (Tc) and improve the thermochromic performance (Tlum and ΔTsol) of VO2-based phases: e.g. W can effectively decrease Tc of VO2 (68°C), but Tlum and ΔTsol are deteriorated; alkaline and rare-earth metals improve Tlum but do not lower substantially Tc. Therefore, a multidimensional search space needs to be explored in order to identify a new multinary material which fulfils all necessary requirements. Thus, to achieve better performance of VO2-based thin films for smart windows, first, V-M1-O systems with unexplored elements for M1 will be investigated in search for elements which reduce Tc and improve Tlum. Then, quaternary systems (V-M1-M2-O) will be explored: synergistic effects of M1 and M2 on the thermochromic properties of VO2 are expected, to achieve lower Tc and higher Tlum. This needs a large experimental dataset which will be accomplished by synthesis of combinatorial materials libraries and their high-throughput characterization. The best identified systems will additionally be fabricated as nanoporous films by glancing angle deposition in order to further enhance Tlum, and a protective antireflective coating will be applied to further optimize Tlum.

• DFG Programme: Research Grants