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Charge transport and glassy dynamics in ionic liquids

Subject Area Physical Chemistry of Molecules, Liquids and Interfaces, Biophysical Chemistry
Term from 2006 to 2013
Project identifier Deutsche Forschungsgemeinschaft (DFG) - Project number 29405857
 
Final Report Year 2015

Final Report Abstract

The interplay between charge transport and glassy dynamics in Ionic Liquids (IL) was at the beginning of the above project a totally open topic. By combining different experimental techniques such as broadband dielectric spectroscopy (BDS), pulsed field gradient nuclear magnetic resonance (PFG-NMR), differential scanning calorimetry (DSC), and dynamic mechanical spectroscopy (DMS), it became possible to develop a full quantitative understanding: Whereas the absolute values of dc conductivity and viscosity vary over more than 11 decades with temperature and upon systematic structural variation of the ILs, agreement is found between the characteristic frequency of charge transport and the structural relaxation. This reflects the fact that charge transport and glassy dynamics in IL can be fully traced back to the equations of rotational and translational diffusion as developed by Einstein, Stokes-Einstein and Einstein-Smoluchowski.

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