New Recyclable Phosphorous Ligands for Regio- and Stereocontrol in Homogeneous Catalysis

• Applicants: Professor Dr. Peter Eilbracht; Professor Dr. Rainer Haag
• Subject Area: Organic Molecular Chemistry - Synthesis and Characterisation
• Term: from 2006 to 2010
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 22730784

• Final Report Year: 2010

Final Report Abstract

No abstract available

Publications

• Dissertation, Universitat Dortmund, 2004. Synthese von Dendrimeren durch Hydroaminomethylierung und ihre Anwendung
  F. Koc
  
• Acta Cryst. 2005, E61, 3115-3116. 10-(tert-butyldimethylsilyl)-4,6-bis(diphenyl-phosphino)phenoxazine
  P. W. Osinski, M. Schürmann, H. Preut, R. Haag
  
• Dissertation, Universität Dortmund, 2005. Dendritic Polyglycerol as a high-loading Support for Organic Synthesis, Reagents, Catalysts, and Drugs
  S. Roller
  
• J. Org. Chem. 2005, 70, 2021-2025. Highly Regioselective Synthesis ofAmino-Functionalized Dendritic Polyglycerols by a One-Pot Hydroformylation/Reductive Amination
  F. Koc, M. Wyszogrodzka, P. Eilbracht, R. Haag
  
• Mol. Div. 2005, 9, 305-316. High-loading polyglycerol supported reagents for Mitsunobu and acylation reactions and other useful polyglycerol derivatives
  S. Roller, H. Zhou, R. Haag
  
• Synthesis 2005,19, 3362-3372. Catalysts on functionalized polymer chips (PC) as recyclable entities
  F. Koc, F. Michalek, L. Rumi, W. Bannwarth, R. Haag
  
• Acta Cryst. 2006, E62, 1248-1249. (-)-Menthyl (SP, RS)-(2-p-tolylsulfinylethyl)-phenylphosphinate
  P. W. Osmski, J. Saadi, S. Ricken, M. Schürmann, H. Preut, P. Eilbracht
  
• Acta Cryst. 2006, E62, 1435-1436. Bis[4-(2-methyl-2-propenyl)piperazin-l-yl]-methane
  S. Ricken, M. Schürmann, H. Preut, P. Eilbracht
  
• Acta Cryst. 2006, E62, 1807-1808. Methyl 3-[4,6-bis(diphenylphosphino)-phenoxazin-10-yl]propionate
  S. Ricken, P. W. Osinski, M. Schürmann, H. Preut, P. Eilbracht
  
• Acta Cryst. 2006, E62, 2637-2638. 4,6-Bis-diphenylphosphanyl-phenoxazine-10-carboxylic acid allylamide
  S. Ricken, M. Schürmann, H. Preut, P. Eilbracht
  
• Acta Cryst. 2006, E62, 2953-2954. (R)-(+)-(tert-Butyl-vinyl-phosphinoyl)-benzene
  A. Szmigielskas, K. M. Pietrusiewicz, S. Ricken, M. Schürmann, H. Preut, P. Eilbracht
  
• Dissertation, Universität Dortmund, 2006. Herstellung von Polyaminen und deren Verwendung als Polymer Support
  S. Ricken
  
• J. Mol. Catal. A: Chem. 2006, 257, 78-88. A new approach to dendritic supported NIXANTPHOS-based hydroformylation catalysts
  S. Ricken, P. Osinski, P. Eilbracht, R. Haag
  
• Org. Biomol. Chem. 2006, 4, 826-835. Synthesis of polyamines via hydroaminomethylation of alkenes with urea - a new, effective and versatile route to dendrons and dendritic core molecules
  K. S. Müller, F. Koc, S. Ricken, P. Eilbracht
  
• Topics in Organometallic Chemistry 2006, 18, 65-95. Synthetic Applications of Tandem Reaction Sequences Involving Hydroformylation
  P. Eilbracht, A. M. Schmidt
  
• Topics in Organometallic Chemistry 2006, 20, 149-176. Hyperbranched polymers as platforms for catalysts
  C. Hajji, R. Haag
  
• Z. Krystallogr. NCS 2006, 455-456. N,N,N',N',N",N"-Hexakis(2-methylallyl)-[1,3,5]-triazin-2,4,6-triamine
  S. Ricken, F. Koc, M. Schürmann, H. Preut, P. Eilbracht
  
• Adv. Synth Catal. 2007, 349,1897-1905. Tandem metal- and organocatalysis in sequential hydroformylation and enantioselective aldol reactions
  S. Chercheja, P. Eilbracht
  
• Adv. Synth CataL 2008, 350, 2903-2909. Polyurethane- and Polystyrene-Supported 2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO); Facile Preparation, Catalytic Oxidation and Application in a Membrane Reactor
  M. A. Subhani, M. Beigi, P. Eilbracht
  
• Dissertation, Technische Universität Dortmund, 2008. Synthesis of New Dendritic Polyamine Compounds
  M. A. Subhani
  
• Org Biomol. Chem. 2008, 6, 4059-4063. Syntheses oftetrahydro-ß-carbolines via a tandem hydroformylation-Pictet-Spengler reaction. Scope and limitations
  B. P. Bondzic, P. Eilbracht
  
• Org. Biomol. Chem. 2008, 3723-3731. Application of iridium catalyzed allylic substitution reactions in the synthesis of branched tryptamines and homologues via tandem hydroformylation-Fischer indole synthesis
  B. P. Bondzic, A. Farwick, J. Liebich, P. Eilbracht
  
• Org. Lett 2008,10, 3433-3436. A novel access to tetrahydro-ß-carbolines via one-pot hydroformylation/Fischer indole synthesis: Rearrangement of 3,3-spiroindoleninium cations
  B. P. Bondzic, P. Eilbracht
  
• Adv. Synth Catal. 2009, 351, 339-344. Tandem Metal and Organocatalysis in Sequential Hydroformylation and Enantioselective Mannich Reactions
  S. Chercheja, T. Rothenhücher, P. Eilbracht
  
• Adv. Synth. Catal. 2009, 557, 2113-2123. Chiral Polyamino Alcohols via Hydroaminomethylation: A New Class of Polyamines for Dendritic Cores and Ligand Precursors
  M. A. Subhani, K.-S. Müller, P. Eilbracht
  
• Dissertation, Freie Universität Berlin, 2009. Modular Synthesis of hyperbranched Polyglycerol supported N-heterocyclic Carbene Ligands for Application in Catalysis
  M. Meise
  
• Org. Biomol. Chem. 2009, 7, 4000-4008. A new one-pot hydroformylation/Strecker synthesis as a versatile synthetic tool for polyfunctional compounds andfunctionalization of dendrimers
  M. A. Subhani, K. S. Müller, F. Koc, P. Eilbracht