Project Details
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Preparation,characterization and applications of perovskite hollow fiber membrane

Subject Area Technical Chemistry
Thermodynamics and Kinetics as well as Properties of Phases and Microstructure of Materials
Term from 2011 to 2015
Project identifier Deutsche Forschungsgemeinschaft (DFG) - Project number 209458269
 
Final Report Year 2015

Final Report Abstract

The following progresses are obtained: (1) CO2-stable oxygen-permeable Fe2O3 (FO) - Ce0.9Gd0.1O2-δ (CGO) dual phase composite membranes were successfully prepared via a one-pot single-step method; (2) A novel cobalt-free and noble metal-free dual phase membrane of the composition 40 wt.% Pr0.6Sr0.4FeO3-δ-60 wt.% Ce0.9Pr0.1O2-δ (40PSFO-60CPO) has been successfully developed via an in-situ one-pot one-step glycine-nitrate combustion process; (3) a novel U-shaped K2NiF4-type oxide hollow-fiber membranes based on (Pr0.9La0.1)2(Ni0.74Cu0.21Ga0.05)O4+δ (PLNCG) were successfully prepared through a phase-inversion spinning process. The effect of CO2 and SO2 on the oxygen permeation, phase structure and the microstructure of the material were investigated.

Publications

  • CO2-stable and cobalt-free dual-phase membrane for oxygen separation, Angew. Chemie Int. Ed. 50, (2011) 759
    Huixia Luo, Konstantin Efimov, Heqing Jiang, Armin Feldhoff, Haihui Wang, Jürgen Caro
  • CO2-tolerant oxygen-permeable Fe2O3-Ce0.9Gd0.1O2-δ dual phase membranes, Industrial & Engineering Chemistry Research, 50 (2011) 13508
    Huixia Luo, Heqing Jiang, Konstantin Efimov, Fangyi Liang, Haihui Wang, Jürgen Caro
  • Influence of the preparation methods on the microstructure and oxygen permeability of a CO2-stable dual phase membrane, AIChE Journal, 58 (2011) 2738
    Huixia Luo, Heqing Jiang, Konstantin Efimov, Jürgen Caro, Haihui Wang
  • Rapid glycine-nitrate combustion synthesis of the CO2-stable dual phase membrane 40Mn1.5Co1.5O4-d–60Ce0.9Pr0.1O2-d for CO2 capture via an oxy-fuel process, Journal of Membrane Science, 422/423 (2012) 450
    Huixia Luo, Heqing Jiang, Tobias Klande, Fangyi Liang, Zhengwen Cao, Haihui Wang, Jürgen Caro
  • Novel Cobalt-Free, Noble Metal-Free Oxygen-Permeable 40Pr0.6Sr0.4FeO3‑δ−60Ce0.9Pr0.1O2−δ Dual-Phase Membrane, Chemistry of Materials 2012, 24, 2148−2154
    Huixia Luo, Heqing Jiang, Tobias Klande, Zhengwen Cao, Fangyi Liang, Haihui Wang, Jürgen Caro
  • A highly active perovskite electrode for the oxygen reduction reaction below 600°C, Angew. Chem. Int. Ed. 52 (2013) 14036
    Wei Zhou, Jaka Sunarso, Mingwen Zhao, Fengli Liang, Tobias Klande, Armin Feldhoff
    (See online at https://doi.org/10.1002/anie.201307305)
  • Dense ceramic oxygen permeable membranes and catalytic membrane reactors, Chemical Engineering Journal 220 (2013) 185
    Yanying Wei,Weishen Yang, Jürgen Caro, Haihui Wang
    (See online at https://doi.org/10.1016/j.cej.2013.01.048)
  • Effect of A-site lanthanum doping on the CO2 tolerance of SrCo0.8Fe0.2O3-δ oxygen-transporting membranes, Journal of Membrane Science 437 (2013) 122
    Tobias Klande, Olga Ravkina, Armin Feldhoff
    (See online at https://doi.org/10.1016/j.memsci.2013.02.051)
  • Effect of CO2 and SO2 on oxygen permeation and microstructure of (Pr0.9La0.1)2(Ni0.74Cu0.21Ga0.05) O4+δ membranes, Journal of Membrane Science 429 (2013) 147
    Yanying Wei, Olga Ravkina, Tobias Klande, Haihui Wang, Armin Feldhof
    (See online at https://doi.org/10.1016/j.memsci.2012.11.075)
  • Effect of microstructure on oxygen permeation of Ba0.5Sr0.5Co0.8Fe0.2O3-δ and SrCo0.8Fe0.2O3-δ membranes, J. Eur. Ceram. Soc. 33 (2013) 1129
    Tobias Klande, Olga Ravkina, Armin Feldhoff
    (See online at https://doi.org/10.1016/j.jeurceramsoc.2012.11.023)
  • Investigation of Zr-doped BSCF perovskite membrane for oxygen separation in the intermediate temperature range, J. Solid State Chem. 201 (2013) 101
    Olga Ravkina, Tobias Klande, Armin Feldhoff
    (See online at https://doi.org/10.1016/j.jssc.2013.02.023)
  • A CO2-stable reduction-tolerant Nd-containing dual phase membrane for oxyfuel CO2 capture, J. Mater. Chem. A 2 (2014) 7780
    Huixia Luo, Tobias Klande, Zhengwen Cao, Fangyi Liang, Haihui Wang, Jürgen Caro
    (See online at https://doi.org/10.1039/c3ta14870j)
  • A novel CO2-stable dual phase membrane with high oxygen permeability, Chem. Commun. 50 (2014) 2451-2454
    Fangyi Liang, Huixia Luo, Kaveh Partovi, Olga Ravkina, Zhengwen Cao, Yi Liu, Jürgen Caro
    (See online at https://doi.org/10.1039/c3cc47962e)
  • High-flux oxygen-transporting membrane Pr0.6Sr0.4Co.5Fe0.5O3-δ: CO2 stability and microstructure, ACS Appl. Mater. Interfaces 6 (2014) 10274-10282
    Kaveh Partovi, Fangyi Liang, Olga Ravkina, Jürgen Caro
    (See online at https://doi.org/10.1021/am501657j)
  • Partial oxidation of methane in hollow-fiber membrane reactors based on alkaline-earth metal-free CO2-tolerant oxide,AIChE Journal 60 (2014) 3587
    Yanying Wei, Qing Liao, Zhong Li, Armin Feldhoff, Jürgen Caro, Haihui Wang
    (See online at https://doi.org/10.1002/aic.14540)
  • Effect of the B-Site Composition on the Oxygen Permeability and the CO2 Stability of Pr0.6Sr0.4CoxFe1–xO3−δ (0.0 ≤ x ≤ 1.0) Membranes. Chemistry of Materials, 2015, 27 (8), pp 2911–2919
    Kaveh Partovi, Benjamin Geppert, Fangyi Liang, Claus Rüscher, Jürgen Caro
    (See online at https://doi.org/10.1021/acs.chemmater.5b00166)
  • Influence of different sintering techniques on microstructure and phase composition of oxygen-transporting ceramic, J. Eur. Ceram. Soc., Journal of the European Ceramic Society Volume 35, Issue 10, September 2015, Pages 2833-2843
    Olga Ravkina, Jan Räthel, Armin Feldhoff
    (See online at https://doi.org/10.1016/j.jeurceramsoc.2015.03.039)
  • Investigation of carbonates in oxygen-transporting membrane ceramic, Journal of Membrane Science 480 (2015) 31
    Olga Ravkina, Tobias Klande, Armin Feldhoff
    (See online at https://doi.org/10.1016/j.memsci.2015.01.042)
  • Novel CO2-tolerant Al-containing membranes for high-temperature oxygen separation. Journal of Materials Chemistry A, Vol 3 Issue 47, 2015, 24008-24015
    Kaveh Partovi, Michael Bittner, Jürgen Caro
    (See online at https://doi.org/10.1039/c5ta04405g)
 
 

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