Introduction of Nitrogen into uranium and thorium halides: Reactions with liquid ammonia, amides, imides, nitrides, and azides

• Applicant: Professor Dr. Florian Kraus
• Subject Area: Inorganic Molecular Chemistry - Synthesis and Characterisation ; Solid State and Surface Chemistry, Material Synthesis
• Term: from 2010 to 2018
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 189244078

• Final Report Year: 2018

Final Report Abstract

No abstract available

Publications

• Uranyl Halides from Liquid Ammonia: [UO2(NH3)5]Cl2∙NH3 and [UO2F2(NH3)3]2∙2NH3 and their Decomposition Products [UO2Cl2(NH3)3] and [UO2F2(NH3)3], Z. Anorg. Allg. Chem. 2012, 638, 2044-2052
  P. Woidy, A. J. Karttunen, F. Kraus
  
• [Th10(µ-F16)(µ3-O4)(µ4-O4)(NH3)32](NO3)8 ∙ 19.6 NH3 – the largest Thorium Complex from Solution known to date, Z. Anorg. Allg. Chem. 2014, 640, 1547-1550
  P. Woidy, F. Kraus
  
• [UO2(NH3)5]Br2∙NH3: Synthesis, Crystal Structure, and Speciation in Liquid Ammonia Solution by First-Principles Molecular Dynamics Simulations, Dalton Trans. 2015, 44, 7332-7337
  P. Woidy, M. Bühl, F. Kraus
  
• The Reactions of TiCl3, and of UF4 with TiCl3 in liquid Ammonia: Unusual Coordination Spheres in [Ti(NH3)8]Cl3∙6NH3 and [UF(NH3)8]Cl3∙3.5NH3, Chem. Commun. 2015, 51, 11826-11829
  P. Woidy, A. J. Karttunen, S. S. Rudel, F. Kraus
  
• A 1D Coordination Polymer of UF5 with HCN as a Ligand – [UF5(HCN)2], Chem. Eur. J. 2017, 23, 291-295
  B. Scheibe, S. S. Rudel, M. R. Buchner, A. J. Karttunen, F. Kraus
  
• Facile Synthesis of Pure Uranium Halides: UCl4, UBr4, UI4, Dalton Trans. 2017, 46, 5835-5842
  S. S. Rudel, F. Kraus
  
• Nanosized Gadolinium and Uranium – Two Representatives of High-Reactivity Lanthanide and Actinide Metal Nanoparticles, ACS Omega 2017, 2, 9144-9149
  C. Schöttle, S. S. Rudel, R. Popescu, J. Treptow, D. Gerthsen, F. Kraus, C. Feldmann
  
• [UCl4(HCN)4] – A hydrogen cyanide complex of uranium tetrachloride, Chem. Commun. 2018, 54, 1241-1244
  S. S. Rudel, C. Pietzonka, M. Hoelzel, F. Kraus
  
• Facile Syntheses of pure Uranium(III) Halides: UF3, UCl3, UBr3, and UI3, Z. Anorg. Allg. Chem. 2018, 644, 323-329
  S. S. Rudel, H. L. Deubner, B. Scheibe, M. Conrad, F. Kraus
  
• Recent Advances in the Chemistry of Uranium Halides in Anhydrous Ammonia, Z. Kristallogr. 2018
  S. S. Rudel, S. A. Baer, P. Woidy, T. G. Müller, H.-L. Deubner, B. Scheibe, F. Kraus