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SPP 1239:  Modification of Microstructure and Shape of Solid Materials by External Magnetic Fields

Subject Area Materials Science and Engineering
Mathematics
Physics
Term from 2006 to 2013
Project identifier Deutsche Forschungsgemeinschaft (DFG) - Project number 18470518
 
Currently applied adaptive materials like piezoceramics or magnetostrictive materials can change their shape by applying an external electric or magnetic field and reach relative length changes of 0.1 to 0.2 per cent. Especially piezoceramic functional materials had been a key requirement for several innovations. Applications range from the scanning tunnelling microscope to novel injection valves.
Another class of adaptive materials are the shape memory alloys, which can exhibit a reversible shape change due to temperature variation. The origin of this effect is the phase transformation between the high temperature "austenite" phase and the low temperature "martensite" phase. In single crystals of special magnetic shape memory materials in 1996 a further, fundamentally new actuation mechanism had been discovered in the martensite phase. It was observed, that already comparably low magnetic fields (< 1 Tesla) can be sufficient to move twin boundaries contained in the material. Since the twin boundaries are separating areas of different crystallographic orientations, their displacement leads to a reorientation of the crystal. This allows controlling the microstructure and shape of the sample by applying magnetic fields. The observed change in length of up to 10 per cent is, compared to magnetostrictive or piezoceramic materials, by more than two orders of magnitude higher. Due to the unique combination of very large strain, high energy density and relatively high actuation frequencies magnetic shape memory alloys thus allow novel applications, which are not possible with conventional adaptive materials.
Within the area A of the Priority Programme, the fundamentals of this material class are examined. Models are developed which describe the coupling of microstructure and magnetism from the atomistic dimensions to the device scale. Additionally, novel magnetic shape memory alloys are prepared and examined which promise better properties compared to today's materials.
Within area B, new and efficient preparation routes for bulk materials are developed. These materials are integrated into novel actuator and damping systems. An additional focus is on the characterisation of these materials with high lateral and temporal resolution.
Area C develops thin films with appropriate microstructure and texture. It is the aim to use the high miniaturisation potential of the magnetic shape memory effect and to develop novel micro actuator and sensor systems.
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