GRK 1626: Chemical Photocatalysis
Final Report Abstract
Die Verwendung von Licht in der Synthesechemie hat im letzten Jahrzehnt eine enorme Renaissance erlebt. Die klassische Photochemie hat, beflügelt durch die Fortschritte in der Beleuchtungstechnik (Licht emittierende Dioden, LEDs), in der Mikroreaktionstechnik und durch die Nutzung von sichtbarem Licht für sensibilisierte photoinduzierte Energie- und Elektronentransferprozesse ein neues Niveau erreicht. Das Graduiertenkolleg „Chemische Photokatalyse“ hat diese Entwicklung von Anfang an begleitet und durch wesentliche Beiträge mit vorangetrieben. Die Bündelung von Expertise aus der Synthesechemie, der Photochemie, der Spektroskopie und der Computerchemie in einem national und international sichtbaren Forschungsschwerpunkt ermöglichte es unter anderem neue photochemische Reaktionsprinzipien unter Verwendung mehrerer Photonen, stereoselektive photochemische Synthesen, Photoreaktionen mit Kupferkomplexen, oder auch mit heterogenen Katalysatoren und Organokatalysatoren zu etablieren. Detaillierte mechanistische Untersuchungen für die auch neue Messapparaturen und Analyseverfahren entwickelt wurden, kennzeichnen viele Arbeiten des Graduiertenkollegs. Wichtige Reaktionsprinzipien und Syntheseanwendungen wurden gefunden, die u.a. in der Wirkstoffforschung Anwendungen finden und die Grundlage für die weitere Entwicklung des Forschungsgebietes bilden. Die Bilanz von über 270 wissenschaftlichen Publikationen und 73 abgeschlossenen Promotionen dokumentieren die sehr erfolgreiche Arbeit des Graduiertenkollegs.
Publications
- Photooxidation of Benzyl Alcohols with Immobilized Flavins. Adv. Synth. Cat. 2009, 351, 163-174
H. Schmaderer, P. Hilgers, R. Lechner, B. König
(See online at https://doi.org/10.1002/adsc.200800576) - Transient memory effect in the photoluminescence of InGaN single quantum wells. Optics Express 2009, 17 (25), 22855-22860
C. Feldmeier, M. Abiko, U. T. Schwarz, Y. Kawakami and R. Micheletto
(See online at https://doi.org/10.1364/oe.17.022855) - [2+2]-Photocycloaddition Reactions of Tetronic Acid Esters and Amides. Synthesis 2010, 2308-2312
J. P. Hehn, D. Gamba-Sánchez, M. Kemmler, M. Fleck, B. Basler, T. Bach
(See online at https://doi.org/10.1055/s-0029-1218793) - A Theoretical Study on the Repair Mechanism of the (6-4) Photolesion by the (6-4) Photolyase. J. Am. Chem. Soc. 2010, 132, 16285-16295
K. Sadeghian, M. Bocola, T. Merz and M. Schütz
(See online at https://doi.org/10.1021/ja108336t) - Green-light photocatalytic reduction using dye-sensitized TiO2 and transition metal nanoparticles. Green Chem. 2010, 400-406
Stefan Füldner, Ralph Mild, Heiko Ingo Siegmund, Josef A. Schroeder, Michael Gruber and Burkhard König
(See online at https://doi.org/10.1039/B918140G) - Laboratory apparatus for the accurate, facile and rapid determination of visible light photoreaction quantum yields. Photochem. Photobiol. Sci. 2010, 9, 1400-1406
Uwe Megerle, Robert Lechner, Burkhard König and Eberhard Riedle
(See online at https://doi.org/10.1039/c0pp00195c) - Laboratory apparatus for the accurate, facile and rapid determination of visible light photoreaction quantum yields. Photochem. Photobiol. Sci. 2010, 9, 1400-1406
Uwe Megerle, Robert Lechner, Burkhard König and Eberhard Riedle
(See online at https://doi.org/10.1039/c0pp00195c) - Mechanism of signal transduction of the LOV2-Jα photosensor from Avena sativa. Nature Communications 2010, 1, 122
Emanuel Peter, Bernhard Dick and Stephan A. Baeurle
(See online at https://doi.org/10.1038/ncomms1121) - Oxidation and Deprotection of Primary Benzyl Amines by Visible Light Flavin Photocatalysis. Synthesis 2010, 1712-1718
Robert Lechner, Burkhard König
(See online at https://doi.org/10.1055/s-0029-1218709) - Visible light flavin photo-oxidation of methylbenzenes, styrenes and phenylacetic acids. Photochem. Photobiol. Sci. 2010, 9, 1367-1377
R. Lechner, S. Kümmel, B. König
(See online at https://doi.org/10.1039/c0pp00202j) - Effect of computational methodology on the conformational dynamics of the protein photosensor LOV1 from Chlamydomonas reinhardtii. J. Chem. Biol. 2011, 4, 167-184
E. Peter, Bernhard Dick, Stephan A. Baeurle
(See online at https://doi.org/10.1007/s12154-011-0060-z) - Enantioselective Intramolecular [2+2]-Photocycloaddition Reactions of 4- Substituted Quinolones Catalyzed by a Chiral Sensitizer with a Hydrogen- Bonding Motif. J. Am. Chem. Soc. 2011, 133, 16689-16697
C. Müller, A. Bauer, M. M. Maturi, M. C. Cuquerella, M. A. Miranda, T. Bach
(See online at https://doi.org/10.1021/ja207480q) - Eosin Y Catalyzed Visible Light Oxidative C-C and C-P bond Formation. Org. Lett. 2011, 13, 3852-3855
Durga Prasad Hari and Burkhard König
(See online at https://doi.org/10.1021/ol201376v) - Flavin-Induced DNA Photooxidation and Charge Movement Probed by Ultrafast Transient Absorption Spectroscopy. ChemBioChem 2011, 12, 703-706
Matthias Wenninger, Danila Fazio, Uwe Megerle, Christian Trindler, Stefan Schiesser, Eberhard Riedle, and Thomas Carell
(See online at https://doi.org/10.1002/cbic.201000730) - Flavin-Induced DNA Photooxidation and Charge Movement Probed by Ultrafast Transient Absorption Spectroscopy. ChemBioChem 2011, 12, 703-706
Matthias Wenninger, Danila Fazio, Uwe Megerle, Christian Trindler, Stefan Schiesser, Eberhard Riedle, and Thomas Carell
(See online at https://doi.org/10.1002/cbic.201000730) - Metal-Free, Cooperative Asymmetric Organophotoredox Catalysis with Visible Light. Angew. Chem. Int. Ed. 2011, 50, 951-954
M. Neumann, S. Füldner, B. König, K. Zeitler
(See online at https://doi.org/10.1002/anie.201002992) - Metal-Free, Cooperative Asymmetric Organophotoredox Catalysis with Visible Light. Angew. Chem. Int. Ed. 2011, 50, 951-954. Synfacts 2010, 12, 1419 - 1419
M. Neumann, S. Füldner, B. König, K. Zeitler
(See online at https://doi.org/10.1002/anie.201002992) - Polar Solvation Dynamics in Water and Methanol: Search for Molecularity. Phys. Chem. Chem. Phys. 2011, 13, 17768-17774
M. Sajadi, M. Weinberger, H.-A. Wagenknecht, N. P. Ernsting
(See online at https://doi.org/10.1039/C1CP21794A) - Real-time near-field evidence of optical blinking in the photoluminescence of InGaN by scanning near-field optical microscope. Optical Materials Express 2011, 1 (2), 158 – 163
K. Oikawa, C. Feldmeier, U. T. Schwarz, Y. Kawakami and R. Micheletto
(See online at https://doi.org/10.1364/OME.1.000158) - Selective Photocatalytic Reductions of Nitrobenzene Derivatives using PbBiO2X and Blue Light. Green Chem. 2011, 13, 640-643
Stefan Füldner, Patrick Pohla, Hanna Bartling, Stephan Dankesreiter, Roland Stadler, Michael Gruber, Arno Pfitzner and Burkhard König
(See online at https://doi.org/10.1039/C0GC00857E) - Selective Photocatalytic Reductions of Nitrobenzene Derivatives using PbBiO2X and Blue Light. Green Chem. 2011, 13, 640-643
Stefan Füldner, Patrick Pohla, Hanna Bartling, Stephan Dankesreiter, Roland Stadler, Michael Gruber, Arno Pfitzner and Burkhard König
(See online at https://doi.org/10.1039/C0GC00857E) - Selective Photocatalytic Reductions of Nitrobenzene Derivatives using PbBiO2X and Blue Light. Green Chem. 2011, 13, 640-643
Stefan Füldner, Patrick Pohla, Hanna Bartling, Stephan Dankesreiter, Roland Stadler, Michael Gruber, Arno Pfitzner and Burkhard König
(See online at https://doi.org/10.1039/C0GC00857E) - Signals of LOV1: a computer simulation study on the wildtype LOV1- domain of Chlamydomonas reinhardtii and its mutants. J. Mol. Mod. 2011, 18, 1375-1388
E. Peter, B. Dick, S. A. Baeurle
(See online at https://doi.org/10.1007/s00894-011-1165-6) - Unraveling the flavin-catalyzed photooxidation of benzylic alcohol with transient absorption spectroscopy from sub-pico- to microseconds. Phys. Chem. Chem. Phys. 2011, 13, 8869-8880
Uwe Megerle, Matthias Wenninger, Roger-Jan Kutta, Robert Lechner, Burkhard König, Bernhard Dick, Eberhard Riedle
(See online at https://doi.org/10.1039/c1cp20190e) - Unraveling the flavin-catalyzed photooxidation of benzylic alcohol with transient absorption spectroscopy from sub-pico- to microseconds. Phys. Chem. Chem. Phys. 2011, 13, 8869-8880
Uwe Megerle, Matthias Wenninger, Roger-Jan Kutta, Robert Lechner, Burkhard König, Bernhard Dick, Eberhard Riedle
(See online at https://doi.org/10.1039/c1cp20190e) - Unraveling the flavin-catalyzed photooxidation of benzylic alcohol with transient absorption spectroscopy from sub-pico- to microseconds. Phys. Chem. Chem. Phys. 2011, 13, 8869-8880
Uwe Megerle, Matthias Wenninger, Roger-Jan Kutta, Robert Lechner, Burkhard König, Bernhard Dick, Eberhard Riedle
(See online at https://doi.org/10.1039/C1CP20190E) - Urea derivatives enhance the photocatalytic activity of dye-modified titanium dioxide. Photochem. Photobiol. Sci. 2011, 10, 623-625
Stefan Füldner, Tatiana Mitkina, Tobias Trottmann, Alexandra Frimberger, Michael Gruber and Burkhard König
(See online at https://doi.org/10.1039/c0pp00374c) - Visible-Light Photoredox Catalysis: Dehalogenation of Vicinal Dibromo-, α- Halo-, and α,α-Dibromocarbonyl Compounds. J. Org. Chem. 2011, 76, 736-739
Tapan Maji, Ananta Karmakar, Oliver Reiser
(See online at https://doi.org/10.1021/jo102239x) - Why BLUF photoreceptors with roseoflavin cofactor loose their biological functionality. Phys. Chem. Chem. Phys. 2011, 13, 14775-14783
Thomas Merz, Keyarash Sadeghian, Martin Schütz
(See online at https://doi.org/10.1039/c1cp21386e) - [Cu(dap)2Cl] As an Efficient Visible-Light-Driven Photoredox Catalyst in Carbon-Carbon Bond-Forming Reactions. Chem. Eur. J. 2012, 18, 7336-7340
Michael Pirtsch, Suva Paria, Taisuke Matsuno, Hiroyuki Isobe, and Oliver Reiser
(See online at https://doi.org/10.1002/chem.201200967) - A novel computer simulation method for simulating the multiscale transduction dynamics of signal proteins. J. Chem. Phys. 2012, 136, 124112
Emanuel Peter, Bernhard Dick, and Stephan A. Baeurle
(See online at https://doi.org/10.1063/1.3697370) - Application of Microflow Conditions to Visible Light Photoredox Catalysis. Org. Lett. 2012, 14, 2658-2661
Matthias Neumann and Kirsten Zeitler
(See online at https://doi.org/10.1021/ol3005529) - Chemical Photocatalysis with 1-(N,N-Dimethylamino)pyrene. Synlett 2012, 23, 2803 - 2807
A. Penner, E. Bätzner, H.-A. Wagenknecht
(See online at https://doi.org/10.1055/s-0032-1317532) - Enantioselective Intramolecular [2+2] Photocycloaddition Reactions of 4- Substituted Coumarins Catalyzed by a Chiral Lewis Acid. Chem. Eur. J. 2012, 18, 7552-7560
Richard Brimioulle, Hao Guo, Thorsten Bach
(See online at https://doi.org/10.1002/chem.201104032) - Hermitian time-dependent coupled-cluster linear response ansätze of second-order in application to excitation energies and frequencydependent dipole polarizabilities. Phys. Rev. A, 2012, 86, 052519
G. Wälz, D. Kats, D. Usvyat, T. Korona and M. Schütz
(See online at https://doi.org/10.1103/PhysRevA.86.052519) - Illuminating the early signaling pathway of a fungal LOV-photoreceptor. Proteins 2012, 80, 471-481
Emanuel Peter, Bernhard Dick, Stephan A. Baeurle
(See online at https://doi.org/10.1002/prot.23213) - Kohls, Paul - Visible Light Photoredox Catalysis: Generation and Addition of N- Aryltetrahydroisoquinoline-Derived α-Amino Radicals to Michael Acceptors. Org. Lett. 2012, 14, 672-675
Paul Kohls, Deepak Jadhav, Ganesh Pandey, Oliver Reiser
(See online at https://doi.org/10.1021/ol202857t) - Metal free, Visible Light Mediated Direct C-H Arylation of Heteroarenes with Aryl Diazonium salts. J. Am. Chem. Soc. 2012, 134, 2958-2961
D. P. Hari, P. Schroll, B. König
(See online at https://doi.org/10.1021/ja212099r) - Metal free, Visible Light Mediated Direct C-H Arylation of Heteroarenes with Aryl Diazonium salts. J. Am. Chem. Soc. 2012, 134, 2958-2961
D. P. Hari, P. Schroll, B. König
(See online at https://doi.org/10.1021/ja212099r) - Phase transition in GeF2 driven by change of type of intermolecular interaction. Phys. Rev. B, 2012, 86, 054102
D. Usvyat, C. Yin, G. Wälz, C. Mühle, M. Schütz and M. Jansen
(See online at https://doi.org/10.1103/PhysRevB.86.054102) - Photocatalytic Arylation of Alkenes, Alkynes and Enones with Diazonium salts. ChemistryOpen 2012, 1, 130-133
Peter Schroll, Durga Prasad Hari, and Burkhard König
(See online at https://doi.org/10.1002/open.201200011) - Photocatalytic Arylation of Alkenes, Alkynes and Enones with Diazonium salts. ChemistryOpen 2012, 1, 130-133
P. Schroll, D. P. Hari, and B. König
(See online at https://doi.org/10.1002/open.201200011) - Signaling pathway of a photoactivable Rac1-GTPase in the early stages. Proteins 2012, 5, 1350-1362
Emanuel Peter, Bernhard Dick, Stephan A. Baeurle
(See online at https://doi.org/10.1002/prot.24031) - Synthesis of a Benzophenone C-Nucleoside as Potential Triplet Energy and Charge Donor in Nucleic Acids. Synthesis 2012, 44, 648-652
M. Weinberger, H.-A. Wagenknecht
(See online at https://doi.org/10.1055/s-0031-1289672) - The role of bridging ligand in hydrogen generation by photocatalytic Ru/Pd assemblies. Dalton Trans. 2012, 41, 13050-13059
Gurmeet Singh Bindra, Martin Schulz, Avishek Paul, Robert Groarke, Suraj Soman, Jane L. Inglis, Wesley R. Browne, Michael G. Pfeffer, Sven Rau, Brian J. MacLean, Mary T. Pryce and Johannes G. Vos
(See online at https://doi.org/10.1039/c2dt30948c) - Visible Light Photocatalytic Synthesis of Benzothiophenes. Org. Lett. 2012, 14, 5334-5337
D. P. Hari, T. Hering, B. König
(See online at https://doi.org/10.1021/ol302517n) - Visible Light Photocatalytic Synthesis of Benzothiophenes. Org. Lett. 2012, 14, 5334-5337
D. P. Hari, T. Hering, B. König
(See online at https://doi.org/10.1021/ol302517n) - Visible-Light-Mediated α-Arylation of Enol Acetates Using Aryl Diazonium Salts. J. Org. Chem. 2012, 77, 10347-10352
T. Hering, D. P. Hari, B. König
(See online at https://doi.org/10.1021/jo301984p) - Visible-Light-Mediated α-Arylation of Enol Acetates Using Aryl Diazonium Salts. J. Org. Chem. 2012, 77, 10347-10352
T. Hering, D. P. Hari, B. König
(See online at https://doi.org/10.1021/jo301984p) - Visible-Light-Promoted Stereoselective Alkylation by Combining Heterogeneous Photocatalysis with Organocatalysis. Angew. Chem. Int. Ed. 2012, 17, 4062-4066
Maria Cherevatskaya, Matthias Neumann, Stefan Füldner, Christoph Harlander, Susanne Kümmel, Stephan Dankesreiter, Arno Pfitzner, Kirsten Zeitler, and Burkhard König
(See online at https://doi.org/10.1002/anie.201108721) - Visible-Light-Promoted Stereoselective Alkylation by Combining Heterogeneous Photocatalysis with Organocatalysis. Angew. Chem. Int. Ed. 2012, 17, 4062-4066
Maria Cherevatskaya, Matthias Neumann, Stefan Füldner, Christoph Harlander, Susanne Kümmel, Stephan Dankesreiter, Arno Pfitzner, Kirsten Zeitler, and Burkhard König
(See online at https://doi.org/10.1002/anie.201108721) - Visible-Light-Promoted Stereoselective Alkylation by Combining Heterogeneous Photocatalysis with Organocatalysis. Angew. Chem. Int. Ed. 2012, 17, 4062-4066
Maria Cherevatskaya, Matthias Neumann, Stefan Füldner, Christoph Harlander, Susanne Kümmel, Stephan Dankesreiter, Arno Pfitzner, Kirsten Zeitler, and Burkhard König
(See online at https://doi.org/10.1002/anie.201108721) - Visible-Light-Promoted Stereoselective Alkylation by Combining Heterogeneous Photocatalysis with Organocatalysis. Angew. Chem. Int. Ed. 2012, 17, 4062-4066
Maria Cherevatskaya, Matthias Neumann, Stefan Füldner, Christoph Harlander, Susanne Kümmel, Stephan Dankesreiter, Arno Pfitzner, Kirsten Zeitler, and Burkhard König
(See online at https://doi.org/10.1002/anie.201108721) - A Cooperative Hydrogen-Bond-Promoted Organophotoredox Catalysis Strategy for Highly Diastereoselective, Reductive Enone Cyclization. Chem. Eur. J. 2013, 19, 6950-6955
Matthias Neumann, Kirsten Zeitler
(See online at https://doi.org/10.1002/chem.201204573) - Aggregation effects in visible light flavin photocatalysts: Synthesis, structure and catalytic activity of 10-arylflavins. Chem. Eur. J. 2013, 19, 1066-1075
Dadová J., Kümmel S., Feldmeier C., Cibulková J., Pažout R., Maixner J., Gschwind R. M., König B., Cibulka R.
(See online at https://doi.org/10.1002/chem.201202488) - Ambient-Light-Mediated Copper-Catalyzed C-C and C-N Bond Formation. Angew. Chem. Int. Ed. 2013, 52, 5919 - 5921
Michal Májek, Axel Jacobi von Wangelin
(See online at https://doi.org/10.1002/anie.201301843) - Chemical Photocatalysis, B. König, De Gruyter 2013, pp. 139-150
O. Reiser, G. Kachkovskyi, V. Kais, P. Kohls, S. Paria, M. Pirtsch, D. Rackl, H. Seo
(See online at https://doi.org/10.1515/9783110269246.139 https://doi.org/10.1039/c4cc10270c) - Conformational control of benzophenone-sensitized charge transfer in dinucleotides. Phys. Chem. Chem. Phys. 2013, 15, 18607-18619
Thomas Merz, Matthias Wenninger, Michael Weinberger, Eberhard Riedle, Hans-Achim Wagenknecht, Martin Schütz
(See online at https://doi.org/10.1039/c3cp52344f) - Conformational control of benzophenone-sensitized charge transfer in dinucleotides. Phys. Chem. Chem. Phys. 2013, 15, 18607-18619
Thomas Merz, Matthias Wenninger, Michael Weinberger, Eberhard Riedle, Hans-Achim Wagenknecht and Martin Schütz
(See online at https://doi.org/10.1039/c3cp52344f) - Conformational control of benzophenone-sensitized charge transfer in dinucleotides. Phys. Chem. Chem. Phys. 2013, 15, 18607-18619
Thomas Merz, Matthias Wenninger, Michael Weinberger, Eberhard Riedle, Hans-Achim Wagenknecht and Martin Schütz
(See online at https://doi.org/10.1039/c3cp52344f) - Description of excited states in photocatalysis with theoretical methods. in: Chemical Photocatalysis (Ed.: B. König), Chapter 14, 263 (2013)
T. Merz and M. Schütz
(See online at https://doi.org/10.1515/9783110269246.263) - Electronic transient spectroscopy from the deep UV to the NIR: unambiguous disentanglement of complex processes. Faraday Disc. 2013;163:139-58
E. Riedle, M. Bradler, M. Wenninger, C. F. Sailer and I. Pugliesi
(See online at https://doi.org/10.1039/c3fd00010a) - Enantioselective Lewis Acid Catalysis of Intramolecular Enone [2+2] Photocycloaddition Reactions. Science 2013, 42, 840-843
R. Brimioulle, T. Bach
(See online at https://doi.org/10.1126/science.1244809) - Heterogeneous semiconductor Photocatalysis (12. Kapitel) in Chemical Photocatalysis, 1. Ausgabe (Hrsg.: B. König), de Gruyter, Berlin, 2013
Eisenhofer, Anna
(See online at https://doi.org/10.1515/9783110269246.211) - Homogeneous visible light-mediated transition metal photoredox catalysis other than ruthenium and iridium. in Chemical Photocatalysis, B. König, De Gruyter 2013, pp. 139-150
O. Reiser, G. Kachkovskyi, V. Kais, P. Kohls, S. Paria, M. Pirtsch, D. Rackl, H. Seo
(See online at https://doi.org/10.1515/9783110269246.139) - Homogeneous visible light-mediated transition metal photoredox catalysis other than ruthenium and iridium. in Chemical Photocatalysis, B. König, De Gruyter 2013, pp. 139-150
O. Reiser, G. Kachkovskyi, V. Kais, P. Kohls, S. Paria, M. Pirtsch, D. Rackl, H. Seo
(See online at https://doi.org/10.1515/9783110269246.139) - Influencing the conductance in biphenyl-like molecular junctions with THz radiation. Phys. Stat. Sol. (b) 2013, 250, 2408
M. Hinreiner, D. A. Ryndyk, D. Usvyat, T. Merz, M. Schütz, K. Richter
(See online at https://doi.org/10.1002/pssb.201349221) - Intramolecular [2+2] Photocycloaddition of 3- and 4-(But-3- enyl)oxyquinolones: Influence of the Alkene Substitution Pattern, Photophysical Studies and Enantioselective Catalysis by a Chiral Sensitizer. Chem. Eur. J. 2013, 19, 7461 - 7472
M. M. Maturi, M. Wenninger, R. Alonso, A. Bauer, A. Pöthig, E. Riedle, T. Bach
(See online at https://doi.org/10.1002/chem.201300203) - Intramolecular [2+2] Photocycloaddition of 3- and 4-(But-3- enyl)oxyquinolones: Influence of the Alkene Substitution Pattern, Photophysical Studies and Enantioselective Catalysis by a Chiral Sensitizer. Chem. Eur. J. 2013, 19, 7461 - 7472
Maturi, M. M.; Wenninger, M.; Alonso, R.; Bauer, A.; Pöthig, A.; Riedle, E.; Bach, T.
(See online at https://doi.org/10.1002/chem.201300203) - Large-scale organization of ribosomal DNA chromatin is regulated by Tip5”. Nucleic Acids Research, 2013, 41, 5251-5262
K. Zillner, M. Filarsky, K. Rachow, M. Weinberger, G. Längst, A. Németh
(See online at https://doi.org/10.1093/nar/gkt218) - LED based NMR Illumination Device for Mechanistic Studies on Photochemical Reactions - Versatile and Simple, yet Surprisingly Powerful. J. Mag. Res. 2013, 32, 39-44
Christian Feldmeier, Hanna Bartling, Eberhard Riedle, Ruth M. Gschwind
(See online at https://doi.org/10.1016/j.jmr.2013.04.011) - LED based NMR Illumination Device for Mechanistic Studies on Photochemical Reactions - Versatile and Simple, yet Surprisingly Powerful. J. Mag. Res. 2013, 32, 39-44
Christian Feldmeier, Hanna Bartling, Eberhard Riedle, Ruth M. Gschwind
(See online at https://doi.org/10.1016/j.jmr.2013.04.011) - LED based NMR illumination device for mechanistic studies on photochemical reactions – versatile and simple, yet surprisingly powerful. Journal of Magnetic Resonance 2013, 232
C. Feldmeier, H. Bartling, E. Riedle, R. M. Gschwind
(See online at https://doi.org/10.1016/j.jmr.2013.04.011) - Organocatalytic Visible Light Mediated Synthesis of Aryl Sulfides. Chem. Commun. 2013, 5507-5509
Michal Májek, Axel Jacobi von Wangelin
(See online at https://doi.org/10.1039/c3cc41867g) - Photocatalytic Surface Patterning of Cellulose using Diazonium Salts and Visible Light. Org. Biomol. Chem. 2013, 11, 6510-6514
P. Schroll, C. Fehl, S. Dankesreiter, B. König
(See online at https://doi.org/10.1039/c3ob40990b) - Photocatalytic Surface Patterning of Cellulose using Diazonium Salts and Visible Light. Org. Biomol. Chem. 2013, 11, 6510-6514
P. Schroll, C. Fehl, S. Dankesreiter, B. König
(See online at https://doi.org/10.1039/c3ob40990b) - Regulatory mechanism of the light-activable allosteric switch LOV-TAP for the control of DNA binding: A computer simulation study. Proteins 2013, 8, 394-405
E. Peter, B. Dick, S. A. Baeurle
(See online at https://doi.org/10.1002/prot.24196) - Synthesis of 4-Aminophthalimide and 2,4-Diaminopyrimidine C- Nucleosides as Isosteric Fluorescent DNA Base Substitutes. J. Org. Chem. 2013, 78, 2589-2599
M. Weinberger, F. Berndt, R. Mahrwald, N. P. Ernsting, H.-A. Wagenknecht
(See online at https://doi.org/10.1021/jo302768f) - Synthetic applications of aryl diazonium salts enabled by visible light photoredox catalysis. Chimica Oggi - Chemistry Today 2013, 31 (4), 59-63
Durga Prasad Hari, Thea Hering, and Burkhard König
(See online at https://doi.org/10.5283/epub.28938) - Synthetic applications of aryl diazonium salts enabled by visible light photoredox catalysis. Chimica Oggi - Chemistry Today 2013, 31 (4), 59-63
Durga Prasad Hari, Thea Hering, and Burkhard König
(See online at https://doi.org/10.5283/epub.28938) - The Photo-Meerwein Arylation: Visible Light Photocatalysis improves a Classic Aryl diazonium Salt Reaction. Angew. Chem. 2013, 52, 4734-4743
D. P. Hari, B. König
(See online at https://doi.org/10.1002/ange.201210276 https://doi.org/10.1002/anie.201210276) - Visible Light-Mediated Synthesis of (Spiro)anellated Furans. Adv. Synth. Catal. 2013, 355, 2240-2248
Georgiy Kachkovskyi, Christian Faderl, Oliver Reiser
(See online at https://doi.org/10.1002/adsc.201300221) - Visible-Light-Induced Intermolecular Atom-Transfer Radical Addition of Benzyl Halides to Olefins: Facile Synthesis of Tetrahydroquinolines. Synthesis 2013, 45, 2689-2698
Suva Paria, Michael Pirtsch, Viktor Kais, Oliver Reiser
(See online at https://doi.org/10.1055/s-0033-1338910) - [2+2] Photocycloaddition of 3-Alkenyloxy-2-cycloalkenones: Enantioselective Lewis Acid Catalysis and Ring Expansion. Angew. Chem. Int. Ed. 2014, 53 (47), 12921-12924
Richard Brimioulle and Thorsten Bach
(See online at https://doi.org/10.1002/anie.201407832) - An improved synthesis of 4-cyano-1,10-phenanthroline, 4,7-dicyano-1,10- phenanthroline and their bis(4,4′-di-tert-butyl-2,2′-bipyridine)ruthenium(II) complexes. Polyhedron 2014, 73, 30-36
Robert Staehle, Roberto Menzel, Katrin Peuntinger, T. David Pilz, Frank W. Heinemann, Dirk M. Guldi, Rainer Beckert, Sven Rau
(See online at https://doi.org/10.1016/j.poly.2014.02.010) - Carbene based photochemical molecular assemblies for solar driven hydrogen generation. Dalton Trans. 2014, 43, 13683-13695
K. Peuntinger, T. D. Pilz, R. Staehle, M. Schaub, S. Kaufhold, L. Petermann, M. Wunderlin, H. Görls, F. W. Heinemann, J. Li, T. Drewello, J. G. Vos, D. M. Guldi, S. Rau
(See online at https://doi.org/10.1039/c4dt01546k) - Carbene based photochemical molecular assemblies for solar driven hydrogen generation. Dalton Trans. 2014, 43, 13683-13695
K. Peuntinger, T. D. Pilz, R. Staehle, M. Schaub, S. Kaufhold, L. Petermann, M. Wunderlin, H. Görls, F. W. Heinemann, J. Li, T. Drewello, J. G. Vos, D. M. Guldi, S. Rau
(See online at https://doi.org/10.1039/c4dt01546k) - Copper in Photocatalysis. ChemCatChem 2014, 6, 2477-2483
Suva Paria, Oliver Reiser
(See online at https://doi.org/10.1002/cctc.201402237) - Enantioselective Catalysis of the Intermolecular [2+2] Photocycloaddition between 2-Pyridones and Acetylenedicarboxylate. Angew. Chem. Int. Ed. 2014, 53 (29), 7661-7664
Mark M. Maturi and Thorsten Bach
(See online at https://doi.org/10.1002/anie.201403885) - Exploring the multiscale signaling behavior of phototropin1 from Chlamydomonas reinhardtii using a full-residue space kinetic Monte Carlo molecular dynamics technique. Proteins 2014, 82 (9), 2018-2040
Emanuel Peter, Bernhard Dick, Ivan Stambolic and Stephan A. Baeurle
(See online at https://doi.org/10.1002/prot.24556) - Ghosh, Tamal - Reduction of aryl halides by consecutive visible light-induced electron transfer processes. Science 2014, 346, 725-728
I. Ghosh, T. Ghosh, J. I. Bardagi, B. König
(See online at https://doi.org/10.1126/science.1258232) - Heterogeneous photocatalysts in organic synthesis. Russian Chemical Reviews 2014, 83, 183-195
M. Cherevatskaya, B. König
(See online at https://doi.org/10.1070/RC2014v083n03ABEH004427) - Light-harvesting of polymerizable 4-hydroxy-1,3-thiazole monomers by energy transfer toward photoactive Os(II) metal complexes in linear polymers. Polym. Chem. 2014, 8, 2715-2724
Alexander M. Breul, Inês Rabelo de Moraes, Roberto Menzel, Michael Pfeffer, Andreas Winter, Martin D. Hager, Sven Rau, Benjamin Dietzek, Rainer Beckert, and Ulrich S. Schubert
(See online at https://doi.org/10.1039/C3PY00915G) - On the Mechanism of Photocatalytic Reactions with Eosin Y. Beilstein J. Org. Chem. 2014, 10, 981-989
M. Májek, F. Filace, A. Jacobi von Wangelin
(See online at https://doi.org/10.3762/bjoc.10.97) - Photocatalytic Generation of Hydrogen from Water under Aerobic Conditions. ChemPlusChem 2014, 11, 1614-1621
R. Staehle, S. Losse, M. R. Filipovic, I. Ivanovic-Burmazovic, J. G. Vos, S. Rau
(See online at https://doi.org/10.1002/cplu.201402174) - Reduction of aryl halides by consecutive visible light-induced electron transfer processes. Science 2014, 346, 725-728
I. Ghosh, T. Ghosh, J. I. Bardagi, B. König
(See online at https://doi.org/10.1126/science.1258232) - Stambolic, Ivan - Exploring the multiscale signaling behavior of phototropin1 from Chlamydomonas reinhardtii using a full-residue space kinetic Monte Carlo molecular dynamics technique. Proteins 2014, 82 (9), 2018-2040
Emanuel Peter, Bernhard Dick, Ivan Stambolic and Stephan A. Baeurle
(See online at https://doi.org/10.1002/prot.24556) - Supramolecular activation of a molecular photocatalyst. Dalton Trans. 2014, 43, 13307-13315
M. G. Pfeffer, C. Pehlken, R. Staehle, D. Sorsche, C. Streb, S. Rau
(See online at https://doi.org/10.1039/c4dt00761a) - Supramolecular activation of a molecular photocatalyst. Dalton Trans. 2014, 43, 13307-13315
M. G. Pfeffer, C. Pehlken, R. Staehle, D. Sorsche, C. Streb, S. Rau
(See online at https://doi.org/10.1039/c4dt00761a) - Synthetic applications of eosin Y in photoredox catalysis. Chem. Commun. 2014, 50, 6688-6699
D. P. Hari, B. König
(See online at https://doi.org/10.1039/c4cc00751d) - The Photoredox-Catalyzed Meerwein Addition Reaction: Intermolecular Amino-Arylation of Alkenes. Angew. Chem. Int. Ed. 2014, 53, 725-728
D. P. Hari, T. Hering, B. König
(See online at https://doi.org/10.1002/anie.201307051) - The Photoredox-Catalyzed Meerwein Addition Reaction: Intermolecular Amino-Arylation of Alkenes. Angew. Chem. Int. Ed. 2014, 53, 725-728
D. Prasad Hari, T. Hering, B. König
(See online at https://doi.org/10.1002/anie.201307051) - Tuning of photocatalytic activity by creating a tridentate coordination sphere for palladium. Dalton Trans. 2014, 43, 11676-11686
M. G. Pfeffer, L. Zedler, S. Kupfer, M. Paul, M. Schwalbe, K. Peuntinger, D. M. Guldi, J. Guthmuller, J. Popp, S. Gräfe, B. Dietzek, S. Rau
(See online at https://doi.org/10.1039/c4dt01034e) - Visible Light Photoredox Catalyzed Cascade Cyclizations of α- Bromochalcones or α-Bromocinnamates with Heteroarenes. Adv. Synth. Catal. 2014, 356, 557-562
S. Paria, O. Reiser
(See online at https://doi.org/10.1002/adsc.201301069) - Visible Light-Mediated Coupling of α-Bromochalcones with Alkenes. Adv. Synth. Catal. 2014, 356, 2853-2858
S. Paria, V. Kais and O. Reiser
(See online at https://doi.org/10.1002/adsc.201400638) - Water Oxidation Catalyzed by Mononuclear Ruthenium Complexes with a 2,2′-Bipyridine-6,6′-dicarboxylate (bda) Ligand: How Ligand Environment Influences the Catalytic Behavior. Inorg. Chem. 2014, 53 (3), 1307-1319
Robert Staehle, Lianpeng Tong, Lei Wang, Lele Duan, Andreas Fischer, Mårten S. G. Ahlquist, Licheng Sun, Sven Rau
(See online at https://doi.org/10.1021/ic401701z) - A search for radical intermediates in the photocycle of LOV domains. Photochem. Photobiol. Sci. 2015, 14, 288-299
Roger Jan Kutta, Kathrin Magerl, Uwe Kensya and Bernhard Dick
(See online at https://doi.org/10.1039/c4pp00155a) - Application of Visible-to-UV Photon Upconversion to Photoredox Catalysis: The Activation of Aryl Bromides. Chem. Eur. J. 2015, 21 (12), 15496-15501
Michal Májek, Uwe Faltermeier, Bernhard Dick, Raúl Pérez-Ruiz, Axel Jacobi von Wangelin
(See online at https://doi.org/10.1002/chem.201502698) - C-H Photooxygenation of Alkyl Benzenes Catalyzed by Riboflavin Tetraacetate and a Non-Heme Iron Catalyst. Angew. Chem. Int. Ed. 2015, 54, 1-5
Bernd Mühldorf, Robert Wolf
(See online at https://doi.org/10.1002/anie.201507170) - Enantioselective Lewis Acid Catalysis in Intramolecular [2+2] Photocycloaddition Reactions: A Mechanistic Comparison between Representative Coumarin and Enone Substrates. J. Am. Chem. Soc. 2015, 137, 5170-5176
R. Brimioulle, A. Bauer, T. Bach
(See online at https://doi.org/10.1021/jacs.5b01740) - Enantioselective Photochemical Rearrangements of Spirooxindole Epoxides Catalyzed by a Chiral Bifunctional Xanthone. Austr. J. Chem. 2015, 68, 1682-1692
Mark M. Maturi, Alexander Pöthig, and Thorsten Bach
(See online at https://doi.org/10.1071/CH15280) - Enantioselektive Katalyse photochemischer Reaktionen. Angew. Chem. 2015, 127 (13), 3944-3963
Richard Brimioulle, Dominik Lenhart, Mark M. Maturi and Thorsten Bach
(See online at https://doi.org/10.1002/ange.201411409) - Enantioselektive Katalyse photochemischer Reaktionen. Angew. Chem. 2015, 127 (13), 3944-3963
Richard Brimioulle, Dominik Lenhart, Mark M. Maturi and Thorsten Bach
(See online at https://doi.org/10.1002/ange.201411409) - LED-beleuchtete NMR-Spektroskopie Flavinkatalysierter Photooxidationen zeigt Lösungsmittelkontrolle des Elektronentransfermechanismus. Angewandte Chemie 2015, 127 (4), 1363–1367
C. Feldmeier, H. Bartling, K. Magerl, R. M. Gschwind
(See online at https://doi.org/10.1002/ange.201409146) - LED-Illuminated NMR Studies of Flavin-Catalyzed Photooxidations Reveal Solvent Control of the Electron-Transfer Mechanism Angew. Chem. Int. Ed. 2015, 54, 1347-1351
C. Feldmeier, H. Bartling, K. Magerl, R.M. Gschwind
(See online at https://doi.org/10.1002/anie.201409146) - LED-Illuminated NMR Studies of Flavin-Catalyzed Photooxidations Reveal Solvent Control of the Electron-Transfer Mechanism. Angew. Chem. Int. Ed. 2015, 54, 1347-1351
C. Feldmeier, H. Bartling, K. Magerl, R.M. Gschwind
(See online at https://doi.org/10.1002/anie.201409146) - LED-Illuminated NMR Studies of Flavin-Catalyzed Photooxidations Reveal Solvent Control of the Electron-Transfer Mechanism. Angew. Chem. Int. Ed. 2015, 54, 1347-1351
C. Feldmeier, H. Bartling, K. Magerl, R.M. Gschwind
(See online at https://doi.org/10.1002/anie.201409146) - Mesoscopic quantum emitters from deterministic aggregates of conjugated polymers. PNAS 2015, 112, E5560-E5566
T. Stangl, P. Wilhelm, K. Remmerssen, S. Höger, J. Vogelsang, and J. M. Lupton
(See online at https://doi.org/10.1073/pnas.1512582112) - Metal-Free Carbonylations by Photo-Redox Catalysis. Angew. Chem. Int. Ed. 2015, 54 (7), 2270-2274
M. Májek, A. Jacobi von Wangelin
(See online at https://doi.org/10.1002/anie.201408516) - No Photocatalyst Required - Versatile, Visible Light Mediated Transformations with Polyhalomethanes. Chem. Commun. 2015, 51, 8280-8283
Johannes F. Franz, Wolfgang B. Kraus, Kirsten Zeitler
(See online at https://doi.org/10.1039/C4CC10270C) - Optimization of Hydrogen-Evolving Photochemical Molecular Devices. Angew. Chem. Int. Ed. 2015, 54, 6627-6631
Michael G. Pfeffer, Tanja Kowacs, Maria Wächtler, Julien Guthmuller, Benjamin Dietzek, Johannes G. Vos, Sven Rau
(See online at https://doi.org/10.1002/anie.201409442) - Palladium versus Platin - das Metall im Katalysezentrum eines molekularen Photokatalysators bestimmt den Mechanismus der Wasserstoffproduktion mit sichtbarem Licht. Angew. Chem. 2015, 127, 5132-5136
Michael G. Pfeffer, Bernhard Schäfer, Grigory Smolentsev, Jens Uhlig, Elena Nazarenko, Julien Guthmuller, Christian Kuhnt, Maria Wächtler, Benjamin Dietzek, Villy Sundström and Sven Rau
(See online at https://doi.org/10.1002/ange.201409438) - Photocatalytic benzylic C-H bond oxidation with a flavin scandium complex. Chem. Commun. 2015, 51, 8425-8428
B. Mühldorf, R. Wolf
(See online at https://doi.org/10.1039/c5cc00178a) - Photocatalytic nucleophilic Addition of alcohols to styrenes in Markovnikov and anti-Markovnikov orientation. Beilstein J. Org. Chem. 2015, 11, 568-575
M. Weiser, S. Hermann, A. Penner, H.-A. Wagenknecht
(See online at https://doi.org/10.3762/bjoc.11.62) - Photocatalytic α-Oxyamination of Stable Enolates, Silyl Enol Ethers, and 2- Oxoalkane Phosphonic Esters. Eur. J. Org. Chem. 2015, 309–313
P. Schroll, B. König
(See online at https://doi.org/10.1002/ejoc.201403433) - Ruthenium Imidazophenanthrolinium Complexes with Prolonged Excited- State Lifetimes. Eur. J. Inorg. Chem. 2015, 3932-3939
Robert Staehle, Christian Reichardt, Jürgen Popp, Dieter Sorsche, Lydia Petermann, Katharina Kastner, Carsten Streb, Benjamin Dietzek, Sven Rau
(See online at https://doi.org/10.1002/ejic.201500021) - Ruthenium Imidazophenanthrolinium Complexes with Prolonged Excited- State Lifetimes. Eur. J. Inorg. Chem. 2015, 3932-3939
Robert Staehle, Christian Reichardt, Jürgen Popp, Dieter Sorsche, Lydia Petermann, Katharina Kastner, Carsten Streb, Benjamin Dietzek, Sven Rau
(See online at https://doi.org/10.1002/ejic.201500021) - Synthesis and characterization of an immobilizable photochemical molecular device for H2-generation. Dalton Trans. 2015, 44, 5577-5586
M. Braumüller, M. Schulz, D. Sorsche, M. Pfeffer, M. Schaub, J. Popp, B.- W. Park, A. Hagfeldt, B. Dietzek, S. Rau
(See online at https://doi.org/10.1039/c4dt03730h) - Synthesis and electronic properties of π-extended flavins. Org. Biomol. Chem. 2015, 13, 10198-10204
Novianti, R. D. Webster, B. König
(See online at https://doi.org/10.1039/c5ob01418b) - Synthetic Strategies for Variably Substituted Ruthenium- Imidazophenanthrolinium Complexes. Eur. J. Inorg. Chem. 2015, 750-762
L. Petermann, R. Staehle, T. D. Pilz, D. Sorsche, H. Görls, S. Rau
(See online at https://doi.org/10.1002/ejic.201402669) - Synthetic Strategies for Variably Substituted Ruthenium- Imidazophenanthrolinium Complexes. Eur. J. Inorg. Chem. 2015, 750-762
L. Petermann, R. Staehle, T. D. Pilz, D. Sorsche, H. Görls, S. Rau
(See online at https://doi.org/10.1002/ejic.201402669) - Temporal Fluctuations in Excimer-Like Interactions between pi-Conjugated Chromophores. J. Phys. Chem. Lett. 2015, 6, 1321-1326
T. Stangl, P. Wilhelm, D. Schmitz, K. Remmerssen, S. Henzel, S.-S. Jester, S. Höger, J. Vogelsang, and J. M. Lupton
(See online at https://doi.org/10.1021/acs.jpclett.5b00328) - Towards Hydrogen Evolution Initiated by LED Light: 2-(1H-1,2,3-Triazol-4- yl)pyridine- Containing Polymers as Photocatalyst. Marcomol. Rapid Commun. 2015, 36, 671-677
Bobby Happ, Joachim Kübel, Michael G. Pfeffer, Andreas Winter, Martin D. Hager, Benjamin Dietzek, Sven Rau, Ulrich S. Schubert
(See online at https://doi.org/10.1002/marc.201400672) - Transition metal complexes with N-heterocyclic carbene ligands: From organometallic hydrogenation reactions toward water splitting. Coord. Chem. Rev. 2015, 304-305, 73-87
S. Kaufhold, L. Petermann, R. Staehle, S. Rau
(See online at https://doi.org/10.1016/j.ccr.2014.12.004) - Transition metal complexes with N-heterocyclic carbene ligands: From organometallic hydrogenation reactions toward water splitting. Coord. Chem. Rev. 2015, 304-305, 73-87
S. Kaufhold, L. Petermann, R. Staehle, S. Rau
(See online at https://doi.org/10.1016/j.ccr.2014.12.004) - Trifluoromethylchlorosulfonylation of Alkenes: Evidence for an Inner- Sphere Mechanism by a Copper Phenanthroline Photoredox Catalyst. Angew. Chem. Int. Ed. 2015, 54, 6999-7002
D. B. Bagal, G. Kachkovskyi, M. Knorn, T. Rawner, B. M. Bhanage, O. Reiser
(See online at https://doi.org/10.1002/anie.201501880) - Visible light C–H amidation of heteroarenes with benzoyl azides. Chem. Sci. 2015, 6, 987-992
E. Brachet, T. Ghosh, I. Ghosh and B. König
(See online at https://doi.org/10.1039/c4sc02365j) - Visible Light Mediated Reductive Cleavage of C-O Bonds Accessing α- Substituted Aryl Ketones. Org. Lett. 2015, 17 (19), 4818-4821
Elisabeth Speckmeier, Clément Padié, Kirsten Zeitler
(See online at https://doi.org/10.1021/acs.orglett.5b02378) - Visible light photocatalytic reduction of aldehydes by Rh(III)– H: a detailed mechanistic study. Chem. Sci. 2015, 6, 2027-2034
T. Ghosh, T. Slanina and B. König
(See online at https://doi.org/10.1039/c4sc03709j) - Visible light photooxidation of nitrate: The dawn of a nocturnal radical.Chemical Communications 2015, 51, 6568-6571
T. Hering, T. Slanina, A. N. Hancock, U. Wille and B. Koenig
(See online at https://doi.org/10.1039/c5cc01580d) - Visible Light-Driven Hydro/Deutero Defunctionalization of Anilines. Chem. Eur. J. 2015, 21 (12), 4518-4522
M. Májek, F. Filace, A. Jacobi von Wangelin
(See online at https://doi.org/10.1002/chem.201406461) - Visible Light-Mediated Metal-Free Synthesis of Vinyl Sulfones from Aryl Sulfinates. Adv. Synth. Cat. 2015, 357, 2050-2054
Andreas Uwe Meyer, Stefanie Jäger, Durga Prasad Hari, and Burkhard König
(See online at https://doi.org/10.1002/adsc.201500142) - Visible Light-Mediated Metal-Free Synthesis of Vinyl Sulfones from Aryl Sulfinates. Adv. Synth. Cat. 2015, 357, 2050-2054
Andreas Uwe Meyer, Stefanie Jäger, Durga Prasad Hari, and Burkhard König
(See online at https://doi.org/10.1002/adsc.201500142) - A Chiral Thiourea as a Template for Enantioselective Intramolecular [2+2] Photocycloaddition Reactions. J. Org. Chem., 2016, 81, 6965-6971
F. Mayr, R. Brimioulle, T. Bach
(See online at https://doi.org/10.1021/acs.joc.6b01039) - A Flow Reactor Setup for Photochemistry of Biphasic Gas/Liquid Reactions. Beilstein J. Org. Chem. 2016, 12, 1798-1811
Josef Schachtner, Patrick Bayer, Axel Jacobi von Wangelin
(See online at https://doi.org/10.3762/bjoc.12.170) - A hierarchy of local Coupled Cluster Singles and Doubles response methods for Ionization Potentials. J. Chem. Phys., 2016, 144, 084117
G. Wälz, D. Usvyat, T. Korona and M. Schütz
(See online at https://doi.org/10.1063/1.4942234) - Chromoselective Photocatalysis: Controlled Bond Activation through Light- Color Regulation of Redox Potentials. Angew. Chem. Int. Ed. 2016, 55 , 7676-7679
I. Ghosh, B. König
(See online at https://doi.org/10.1002/anie.201602349) - Enantioselective [4+4] photodimerization of anthracene-2,6-dicarboxylic acid mediated by a C2-symmetric chiral template. Chem. Commun. 2016, 52, 1032-1035
M. M. Maturi, G. Fukuhara, K. Tanaka, Y. Kawanami, T. Mori, Y. Inoue, T. Bach
(See online at https://doi.org/10.1039/c5cc09107a) - Enantioselective Intermolecular [2+2] Photocycloaddition Reactions of 2(1H)-Quinolones Induced by Visible Light Irradiation. J. Am. Chem. Soc. 2016, 138 (25), 7808-7811
Andreas Tröster, Rafael Alonso, Andreas Bauer, and Thorsten Bach
(See online at https://doi.org/10.1021/jacs.6b03221) - Eosin Y (EY) Photoredox-Catalyzed Sulfonylation of Alkenes: Scope and Mechanism. Chem. Eur. J. 2016, 22 (25), 8694-8699
Andreas Uwe Meyer, Karolína Straková, Tomáš Slanina, Burkhard König
(See online at https://doi.org/10.1002/chem.201601000) - Halogenase-Inspired Oxidative Chlorination Using Flavin Photocatalysis. Angew. Chem. Int. Ed. 2016, 55 (17), 5342-5345
Thea Hering, Bernd Mühldorf, Robert Wolf, Burkhard König
(See online at https://doi.org/10.1002/anie.201600783) - Halogenase-Inspired Oxidative Chlorination Using Flavin Photocatalysis. Angew. Chem. Int. Ed. 2016, 55 (17), 5342-5345
Thea Hering, Bernd Mühldorf, Robert Wolf, Burkhard König
(See online at https://doi.org/10.1002/anie.201600783) - Isosteric and fluorescent DNA base pair formed by 4-amino-phthalimide and 2,4-diaminopyrimidine: melting, structure, and THz polar solvation dynamics. Phys. Chem. Chem. Phys., 2016, 18, 6813-6820
L. Dehmel, F. Berndt, M. Weinberger, M. Sajadi, I. Ioffe, H.-A. Wagenknecht, N. P. Ernsting
(See online at https://doi.org/10.1039/c5cp06972f) - Mechanistic Perspectives on Organic Photoredox Catalysis for Aromatic Substitutions. Acc. Chem. Res. 2016, 49, 2316-2327
Michal Májek, Axael Jacobi von Wangelin
(See online at https://doi.org/10.1021/acs.accounts.6b00293) - Metal-Free C-H Sulfonamidation of Pyrroles by Visible Light Photoredox Catalysis. Chem. Commun. 2016, 52, 10918-10921
Andreas Meyer, Anna Lucia Berger, and Burkhard König
(See online at https://doi.org/10.1039/c6cc06111g) - Metal-Free C-H Sulfonamidation of Pyrroles by Visible Light Photoredox Catalysis. Chem. Commun. 2016, 52, 10918-10921
Andreas Meyer, Anna Lucia Berger, and Burkhard König
(See online at https://doi.org/10.1039/c6cc06111g) - Metal-Free Perfluoroarylation by Visible Light Photoredox Catalysis. ACS Catal. 2016, 6, 369-375
Andreas U. Meyer, Tomáš Slanina, Chang-Jiang Yao, and Burkhard König
(See online at https://doi.org/10.1021/acscatal.5b02410) - Metal-Free Photocatalyzed Cross Coupling of Bromoheteroarenes with Pyrroles. ACS Catal. 2016, 6, 6780-6784
L. Marzo, I. Ghosh, F. Esteban, B. König
(See online at https://doi.org/10.1021/acscatal.6b01452) - Metal-Free Photocatalyzed Cross Coupling of Bromoheteroarenes with Pyrroles. ACS Catal. 2016, 6, 6780-6784
L. Marzo, I. Ghosh, F. Esteban, B. König
(See online at https://doi.org/10.1021/acscatal.6b01452) - Oxygen-Dependent Photocatalytic Water Reduction with a Ruthenium(imidazolium) Chromophore and a Cobaloxime Catalyst. Chem. Eur. J. 2016, 22, 8240-8253
Lydia Petermann, Robert Staehle, Maxim Pfeifer, Christian Reichardt, Dieter Sorsche, Maria Wächtler, Jürgen Popp, Benjamin Dietzek, Sven Rau
(See online at https://doi.org/10.1002/chem.201505113) - Oxygen-Dependent Photocatalytic Water Reduction with a Ruthenium(imidazolium) Chromophore and a Cobaloxime Catalyst. Chem. Eur. J. 2016, 22, 8240-8253
Lydia Petermann, Robert Staehle, Maxim Pfeifer, Christian Reichardt, Dieter Sorsche, Maria Wächtler, Jürgen Popp, Benjamin Dietzek, Sven Rau
(See online at https://doi.org/10.1002/chem.201505113) - Photocatalytic activation of N-chloro compounds for the chlorination of arenes. Tetrahedron 2016, 72, 7821-7825
T. Hering, B. König
(See online at https://doi.org/10.1016/j.tet.2016.06.028) - Photocatalytic Anion Oxidation and Applications in Organic Synthesis. J. Org. Chem. 2016, 81 (16), 6927-6936
Thea Hering, Andreas Uwe Meyer, and Burkhard König
(See online at https://doi.org/10.1021/acs.joc.6b01050) - Photocatalytic Anion Oxidation and Applications in Organic Synthesis. J. Org. Chem. 2016, 81 (16), 6927-6936
Thea Hering, Andreas Uwe Meyer, and Burkhard König
(See online at https://doi.org/10.1021/acs.joc.6b01050) - Radical Reactions Induced by Visible Light in Dichloromethane Solutions of Hünig’s Base: Synthetic Applications and Mechanistic Observation. Chem. Eur. J. 2016, 22, 15921-15928
A. Böhm, T. Bach
(See online at https://doi.org/10.1002/chem.201603303) - Recent Advances in the Synthesis of Cyclobutanes by Olefin [2+2] Photocycloaddition Reactions. Chem. Rev. 2016, 116 (17), 9748-9815
Saner Poplata, Andreas Tröster, You-Quan Zou, Thorsten Bach
(See online at https://doi.org/10.1021/acs.chemrev.5b00723) - Studies of a photochromic model system using NMR with ex-situ and insitu irradiation devices. Magnetic Resonance in Chemistry 2016, 54 (6), 485-491
C. Wolff, J. Kind, H. Schenderlein, H. Bartling, C. Feldmeier, R.M. Gschwind, M. Biesalski, C.M. Thiele
(See online at https://doi.org/10.1002/mrc.4403) - Studies of a photochromic model system using NMR with ex-situ and insitu irradiation devices. Magnetic Resonance in Chemistry 2016, 54 (6), 485-491
C. Wolff, J. Kind, H. Schenderlein, H. Bartling, C. Feldmeier, R.M. Gschwind, M. Biesalski, C.M. Thiele
(See online at https://doi.org/10.1002/mrc.4403) - Synthesis of Pyrrolo[1,2a]quinolines and Ullazines by Visible Light mediated one‐ and twofold Annulation of N-Arylpyrroles with Arylalkynes. Chem. Commun. 2016, 52 , 8695-8698
A. Das, I. Ghosh, B. König
(See online at https://doi.org/10.1039/c6cc04366f) - Synthesis of Pyrrolo[1,2a]quinolines and Ullazines by Visible Light mediated one‐ and twofold Annulation of N-Arylpyrroles with Arylalkynes. Chem. Commun. 2016, 52 , 8695-8698
A. Das, I. Ghosh, B. König
(See online at https://doi.org/10.1039/c6cc04366f) - Synthesis of Supramolecular Iridium Catalysts and Their Use in Enantioselective Visible-Light-Induced Reactions. Synlett 2016, 27 (07), 1056-1060
A. Böhm, T. Bach
(See online at https://doi.org/10.1055/s-0035-1561378) - Synthesis of Trifluoromethylated Sultones From Alkenols Using a Copper Photoredox Catalyst. J. Org. Chem. 2016, 18, 7139-7147
T. Rawner, M. Knorn, E. Lutsker, A. Hossain, O. Reiser
(See online at https://doi.org/10.1021/acs.joc.6b01001) - Synthesis of β-Hydroxysulfones from Sulfonyl Chlorides and Alkenes Utilizing Visible Light Photocatalytic Sequences. Org. Lett. 2016, 18, 2106-2109
S. K. Pagire, S. Paria, O. Reiser
(See online at https://doi.org/10.1021/acs.orglett.6b00734) - The Photocatalyzed Aza-Henry Reaction of N-Aryltetrahydroisoquinolines: Comprehensive Mechanism, H⋅-versus H+-Abstraction, and Background Reactions. J. Am. Chem. Soc. 2016, 138, 11860-11871
Hanna Bartling, Anna Eisenhofer, Burkhard König, and Ruth M. Gschwind
(See online at https://doi.org/10.1021/jacs.6b06658) - The Photocatalyzed Aza-Henry Reaction of NAryltetrahydroisoquinolines: Comprehensive Mechanism, H⋅-versus H+-Abstraction, and Background Reactions. J. Am. Chem. Soc. 2016, 138, 11860-11871
Hanna Bartling, Anna Eisenhofer, Burkhard König, and Ruth M. Gschwind
(See online at https://doi.org/10.1021/jacs.6b06658) - Visible light amination/Smiles cascade: access to phthalazine derivatives. Chem. Sci. 2016, 7, 5002-5006
E. Brachet, L. Marzo, M. Selkti, B. König, P. Belmont
(See online at https://doi.org/10.1039/c6sc01095d) - Visible light amination/Smiles cascade: access to phthalazine derivatives. Chem. Sci. 2016, 7, 5002-5006
E. Brachet, L. Marzo, M. Selkti, B. König, P. Belmont
(See online at https://doi.org/10.1039/c6sc01095d) - Visible Light Mediated Photoredox Catalytic Arylation Reactions. Acc. Chem. Res. 2016, 49, 1566-1577
I. Ghosh, L. Marzo, A. Das, R. Shaikh, B. König
(See online at https://doi.org/10.1021/acs.accounts.6b00229) - Visible Light Mediated Photoredox Catalytic Arylation Reactions. Acc. Chem. Res. 2016, 49, 1566-1577
I. Ghosh, L. Marzo, A. Das, R. Shaikh, B. König
(See online at https://doi.org/10.1021/acs.accounts.6b00229) - Visible Light Mediated Photoredox Catalytic Arylation Reactions. Acc. Chem. Res. 2016, 49, 1566-1577
I. Ghosh, L. Marzo, A. Das, R. Shaikh, B. König
(See online at https://doi.org/10.1021/acs.accounts.6b00229) - Visible-Light Photo-Arbuzov Reaction of Aryl Bromides and Trialkyl Phosphites Yielding Aryl Phosphonates. ACS Catal. 2016, 6, 8410-8414
R. S. Shaikh, S. J. S. Düsel, B. König
(See online at https://doi.org/10.3762/bjoc.12.229) - "Trojan Horse" Effect in Photocatalysis - How Anionic Silver Impurities Influence Apparent Catalytic Activity. Chem. Eur. J. 2017, 23, 2271-2274
Simon Kaufhold, Lydia Petermann, Dieter Sorsche, Sven Rau
(See online at https://doi.org/10.1002/chem.201605391) - A systematic study of the influence of mesoscale structuring on the kinetics of a chemical reaction. Phys. Chem. Chem. Phys. 2017, 19, 23773-23780
Sebastian Krickl, Thomas Buchecker, Andreas Meyer, Isabelle Grillo, Didier Touraud, Pierre Bauduin, Burkhard König, Arno Pfitzner, Werner Kunz
(See online at https://doi.org/10.1039/c7cp02134h) - A systematic study of the influence of mesoscale structuring on the kinetics of a chemical reaction. Phys. Chem. Chem. Phys. 2017, 19, 23773-23780
Sebastian Krickl, Thomas Buchecker, Andreas Meyer, Isabelle Grillo, Didier Touraud, Pierre Bauduin, Burkhard König, Arno Pfitzner, Werner Kunz
(See online at https://doi.org/10.1039/c7cp02134h) - Aromatic Chlorosulfonylation by Photoredox Catalysis. ChemSusChem 2017, 10, 151-155
M. Májek, M. Neumeier, A. Jacobi von Wangelin
(See online at https://doi.org/10.1002/cssc.201601293) - Carboxylation of Aromatic and Aliphatic Bromides and Triflates with CO2 by Dual Visible-Light-Nickel Catalysis. Angew. Chem. Int. Ed. 2017, 56, 13426-13430
Q.-Y. Meng, S. Wang, B. König
(See online at https://doi.org/10.1002/anie.201706724) - Desyl and Phenacyl as Versatile, Photocatalytically Cleavable Protecting Groups: A Classic Approach in a Different (Visible) Light. ACS Catal. 2017, 7, 6821-6826
Elisabeth Speckmeier, Kirsten Zeitler
(See online at https://doi.org/10.1021/acscatal.7b02117) - Direct C-H Phosphonylation of Electron Rich Arenes and Heteroarenes by Visible-Light Photoredox Catalysis. Chem. Eur. J. 2017, 23, 12120-12124
R. S. Shaikh, I. Ghosh, B. König
(See online at https://doi.org/10.1002/chem.201701283) - Lanthanide Ions Coupled with Photoinduced Electron Transfer Generate Strong Reduction Potentials from Visible Light. Chem. Eur. J. 2017, 23, 7900-7904
Andreas Uwe Meyer, Tomáš Slanina, Alexander Heckel, Burkhard König
(See online at https://doi.org/10.1002/chem.201701665) - Molecular polygons probe the role of intramolecular strain in the photophysics of pi-conjugated chromophores. Angew. Chem. Int. Ed. 2017, 56, 1234
P. Wilhelm, J. Vogelsang, G. Poluektov, N. Schönfelder, T. J. Keller, S.-S. Jester, S. Höger, and J. M. Lupton
(See online at https://doi.org/10.1002/anie.201610723) - Photocatalytic N-Formylation of Amines via a Reductive Quenching Cycle in the Presence of Air. Org. Biomol. Chem. 2017, 15, 2536-2540
T. Ghosh, A. Das, B. König
(See online at https://doi.org/10.1039/c7ob00250e) - Photocatalytic N-Formylation of Amines via a Reductive Quenching Cycle in the Presence of Air. Org. Biomol. Chem. 2017, 15, 2536-2540
T. Ghosh, A. Das, B. König
(See online at https://doi.org/10.1039/c7ob00250e) - Photocatalytic oxidation of sulfinates to vinyl sulfones with cyanamidefunctionalised carbon nitride. Eur. J. Org. Chem. 2017, 15, 2179-2185
Andreas Uwe Meyer, Vincent Wing-hei Lau, Burkhard König, Bettina Valeska Lotsch
(See online at https://doi.org/10.1002/ejoc.201601637) - Photocatalytic Phenol-Arene C-C and C-O Cross-Dehydrogenative Coupling. Eur. J. Org. Chem. 2017, 15, 2194-2204
A. Eisenhofer, J. Hioe, R. Gschwind, B. König
(See online at https://doi.org/10.1002/ejoc.201700211) - Photosensitised regioselective [2+2]-cycloaddition of cinnamates and related alkene. Chem. Commun. 2017, 53, 12072-12075
S. K. Pagire, A. Hossain, L. Traub, S. Kerres, O. Reiser
(See online at https://doi.org/10.1039/C7CC06710K) - Photosensitised regioselective [2+2]-cycloaddition of cinnamates and related alkenes. Chem. Commun. 2017, 53, 12072-12075
S. K. Pagire, A. Hossain, L. Traub, S. Kerres, O. Reiser
(See online at https://dx.doi.org/10.1039/c7cc06710k) - Photosensitised regioselective [2+2]-cycloaddition of cinnamates and related alkenes. Chem. Commun. 2017, 53, 12072-12075
S. K. Pagire, A. Hossain, L. Traub, S. Kerres, O. Reiser
(See online at https://dx.doi.org/10.1039/c7cc06710k) - Quantum dots in visible light photoredox catalysis: Reductive dehalogenations and C-H arylation reactions using aryl bromides. Chemistry of Materials 2017, 29, 5225-5231
A. Pal, I. Ghosh, S. Sapra, B. König
(See online at https://doi.org/10.1021/acs.chemmater.7b01109) - Radical Aromatic Trifluoromethylthiolation: Photoredox Catalysis vs. Base Mediation. Eur. J. Org. Chem. 2017, 6722-6725
Denis Koziakov, Michal Májek, Axel Jacobi von Wangelin
(See online at https://doi.org/10.1002/ejoc.201701339) - Reply to "Photoredox Catalysis: The Need to Elucidate the Photochemical Mechanism". Angew. Chem. Int. Ed. 2017, 56, 12822-12824
I. Ghosh, J. I. Bardagi, B. König
(See online at https://doi.org/10.1002/anie.201707594) - Selective Single C(sp3)-F Bond Cleavage in Trifluoromethylarenes: Merging Visible-Light Catalysis with Lewis Acid Activation. J. Am. Chem. Soc. 2017, 139, 18444-18447
K. Chen, N. Berg, R. Gschwind, B. König
(See online at https://doi.org/10.1021/jacs.7b10755) - Sensitization-Initiated Electron Transfer for Photoredox Catalysis. Angew. Chem. Int. Ed. 2017, 56, 8544-8549
I. Ghosh, R. S. Shaikh, B. König
(See online at https://doi.org/10.1002/anie.201703004) - Switching from adduct formation to electron transfer in a light–oxygen–voltage domain containing the reactive cysteine. PCCP 2017, 19(17), 10808-10819
K. Magerl, I. Stambolic, B. Dick
(See online at https://doi.org/10.1039/C6CP08370F) - Synthesis of Arylated Nucleobases by Visible Light Photoredox Catalysis. J. Org. Chem. 2017, 82, 3552-3560
A. Graml, I. Ghosh, B. König
(See online at https://doi.org/10.1021/acs.joc.7b00088) - Visible-light photoredox-catalyzed desulfurization of thiol- and disulfidecontaining amino acids and small peptides. J. Pept. Sci. 2017, 23, 556-562
M. Lee, S. Neukirchen, C. Cabrele, O. Reiser
(See online at https://doi.org/10.1002/psc.3016) - Visible-Light-Accelerated C–H Sulfinylation of Heteroarenes. Angew. Chem. Int. Ed. 2017, 56, 409-412C–H. Sulfinylierung von Heteroaromaten beschleunigt durch sichtbares Licht.A. U. Meyer, A. Wimmer, B. König. Angew. Chem. 2017, 129, 420-423
A. U. Meyer, A. Wimmer, B. König
(See online at https://doi.org/10.1002/anie.201610210 https://doi.org/10.1002/ange.201610210) - Visible-Light-Driven Aerobic Photooxidation of Aldehydes to Methyl Esters Catalyzed by Riboflavin Tetraacetate. ChemCatChem 2017, 9, 920-923
B. Mühldorf, R. Wolf
(See online at https://doi.org/10.1002/cctc.201601504) - Visible-Light-Mediated Radical Arylation of Anilines with Acceptor- Substituted (Hetero)aryl Halides. Org. Lett. 2017, 19, 5976-5979
L. Marzo, S. Wang, B. König
(See online at https://doi.org/10.1021/acs.orglett.7b03001) - Visible-Light-Mediated Synthesis of Pyrazines from Vinyl Azides Utilizing a Photocascade Process. Synlett 2017, 28, 1707-1714 (special issue Heterocycles)
A. Hossain, S. K. Pagire, O. Reiser
(See online at https://doi.org/10.1055/s-0036-1590888) - 1,10-Phenanthroline-dithiine iridium and ruthenium complexes: synthesis, characterization and photocatalytical dihydrogen evolution. Photochemistry & Photobiological Sciences 2018, 17, 1056-1067
E. Erdmann, A. Villinger, B. König, W. W. Seidel
(See online at https://doi.org/10.1039/C8PP00068A) - A synergistic LUMO lowering strategy using Lewis acid catalysis in water to enable photoredox catalytic, functionalizing C–C cross-coupling of styrenes. Chem. Sci.2018, 9, 7096–7103
Elisabeth Speckmeier, Patrick J. W. Fuchs, Kirsten Zeitler
(See online at https://doi.org/10.1039/c8sc02106f) - A Toolbox Approach to Construct Broadly Applicable Metal-Free Catalysts for Photoredox Chemistry – Deliberate Tuning of Redox Potentials and Importance of Halogens in Donor-Acceptor Cyanoarenes. J. Am. Chem. Soc. 2018, 140, 15353–15365
Elisabeth Speckmeier, Tillmann G.Fischer, Kirsten Zeitler
(See online at https://doi.org/10.1021/jacs.8b08933) - Air-sensitive Photoredox Catalysis Performed under Aerobic Conditions in Gel Networks. J. Org. Chem. 2018, 83, 7828-7938
M. Häring, A. Abramov, K. Okumura, I. Ghosh, B. König, N. Yanai, N. Kimizuka, D. Díaz Díaz
(See online at https://doi.org/10.1021/acs.joc.8b00797) - Anthraquinones as photoredox catalysts for the reductive activation of aryl halides. Eur. J. Org. Chem. 2018, 34-40
J. Bardagi, I. Ghosh, M. Schmalzbauer, T. Ghosh, B. König
(See online at https://doi.org/10.1002/ejoc.201701461) - Anthraquinones as photoredox catalysts for the reductive activation of aryl halides. Eur. J. Org. Chem. 2018, 34-40
J. Bardagi, I. Ghosh, M. Schmalzbauer, T. Ghosh, B. König
(See online at https://doi.org/10.1002/ejoc.201701461) - Arene Functionalization by Visible Light Photoredox Catalysis. in: Visible Light Photocatalysis in Organic Chemistry; Edited by Corey R. J. Stephenson, Tehshik P. Yoon, and David W. C. MacMillan, Wiley-VCH 2018, Kap. 8, S. 253 ISBN 978-3-527-33560- 2
D. P. Hari, T. Hering, B. König
(See online at https://doi.org/10.1002/9783527674145.ch8) - Catalytic deracemization of chiral allenes by sensitized excitation with visible light. Nature 2018, 564, 240-243
Alena Hölzl-Hobmeier, Andreas Bauer, Alexandre Vieira Silva, Stefan M. Huber, Christoph Bannwarth, Thorsten Bach
(See online at https://doi.org/10.1038/s41586-018-0755-1) - Chemical Photocatalysis with Rhodamine 6G: Investigation of 2 Photoreduction by Simultaneous Fluorescence Correlation 3 Spectroscopy. J. Phys. Chem. B 2018, 122, 10728-10735
J. M. Haimerl, I. Ghosh, B. König, J. M. Lupton, J. Vogelsang
(See online at https://doi.org/10.1021/acs.jpcb.8b08615) - Coupling photoredox and biomimetic catalysis for the visible-light-driven oxygenation of organic compounds. Physical Sciences Reviews, vol. 4, no. 3, 2019, pp. 20180030
B. Mühldorf, U. Lennert, R. Wolf
(See online at https://doi.org/10.1515/psr-2018-0030) - Coupling photoredox and biomimetic catalysis for the visible-light-driven. Physical Sciences Reviews
B. Mühldorf, U. Lennert, R. Wolf
(See online at https://doi.org/10.1515/psr-2018-0030) - Description of excited states in photochemistry with theoretical methods. Phys. Sci. Rev. 2018, 3, 20170178
T. Merz, G. Bierhance, E.-C. Flach, D Kats, D. Usvyat and M. Schütz
(See online at https://doi.org/10.1515/psr-2017-0178) - Dichromatic Photocatalytic Substitutions of Aryl Halides with a Small Organic Dye. Chem. Eur. J. 2018, 24, 105-108
Michael Neumeier, Diego Sampedro, Michal Májek, Victor A. de la Peña O'Shea, Axel Jacobi von Wangelin, Raúl Pérez-Ruiz
(See online at https://doi.org/10.1002/chem.201705326) - Gigl, Dominik – Haimerl, Josef - Chemical Photocatalysis with Rhodamine 6G: Investigation of 2 Photoreduction by Simultaneous Fluorescence Correlation 3 Spectroscopy and Fluorescence Lifetime Measurements. J. Phys. Chem. B 2018, 122, 10728-10735
J. M. Haimerl, I. Ghosh, B. König, J. M. Lupton, J. Vogelsang
(See online at https://doi.org/10.1021/acs.jpcb.8b08615) - Ligand-Controlled Regioselective Hydrocarboxylation of Styrenes with CO2 by Combining Visible Light and Nickel Catalysis. J. Am. Chem. Soc. 2018, 140, 3198-3201
Q.-Y. Meng, S. Wang, G. S. Huff, B. König
(See online at https://doi.org/10.1021/jacs.7b13448) - Mechanism and cis/trans Selectivity of Vinylogous Nazarov-Type [6π] Photocyclizations. J. Org. Chem. 2018, 83, 964-972
S. Pusch, A. Tröster, D. Lefrancois, P. Farahani, A. Dreuw, T. Bach, T. Opatz
(See online at https://doi.org/10.1021/acs.joc.7b02982) - Molecular excitonic seesaw. PNAS 2018, 115, E3626-E3634
P. Wilhelm, J. Schedlbauer, F. Hinderer, D. Hennen, S. Höger, J. Vogelsang, and J. M. Lupton
(See online at https://doi.org/10.1073/pnas.1722229115) - Photocatalysis with Nucleic Acids and Peptides. Physical Sciences Reviews, 2018, 3
A. Kuhlmann, S. Hermann, M. Weinberger, A. Penner, H.-A. Wagenknecht
(See online at https://doi.org/10.1515/psr-2017-0170) - Photocatalytic Barbier Reaction - Visible-Light induced Allylation and Benzylation of Aldehydes and Ketones. Chem. Sci. 2018, 9, 7230-7235
A. L. Berger, K. Donabauer, B. König
(See online at https://doi.org/10.1039/c8sc02038h) - Photocatalytic Barbier Reaction - Visible-Light induced Allylation and Benzylation of Aldehydes and Ketones. Chem. Sci. 2018, 9, 7230-7235
A. L. Berger, K. Donabauer, B. König
(See online at https://doi.org/10.1039/c8sc02038h) - Photocatalytic formation of carbon-sulfur bonds. J. Org. Chem. 2018, 14, 54-83
D. Petzold, B. König
(See online at https://doi.org/10.3762/bjoc.14.4) - Photocatalytic Oxidative Bromination of Electron-Rich Arenes and Heteroarenes by Anthraquinone. Adv. Synth. Catal. 2018, 360, 626-630
D. Petzold, B. König
(See online at https://doi.org/10.1002/adsc.201701276) - Photoredox catalytic organic transformations using heterogeneous carbon nitrides. Angew. Chem. Int. Ed. 2018, 57, 2-14
A. Savateev, I. Ghosh, B. König, M. Antonietti
(See online at https://doi.org/10.1002/anie.201802472) - Reinventing the De Mayo Reaction: Synthesis of 1,5-Diketones or 1,5- Ketoesters via Visible Light [2+2] Cycloaddition of β-Diketones or β- Ketoesters with Styrenes. Chem. Commun. 2018, 54, 11602-11605
R. Martinez-Haya, L. Marzo, B. König
(See online at https://doi.org/10.1039/c8cc07044j) - Single-molecule photoredox catalysis. Chemical Science 2018, 10, 681
J. M. Haimerl, I. Ghosh, B. König, J. Vogelsang and J. M. Lupton
(See online at https://doi.org/10.1039/c8sc03860k) - Stereoselective Photooxidations by the Schenck Ene Reaction. ChemPhotoChem 2018, 559-570
Axel Jacobi von Wangelin, Raúl Pérez-Ruiz, Patrick Bayer
(See online at https://doi.org/10.1002/cptc.201800058) - Synthesis of aryl sulfides via radical–radical cross coupling of electron-rich arenes using visible light photoredox catalysis. Beilstein J. Org. Chem. 2018, 14, 2520-2528
A. Das, M. Maity, S. Malcherek, B. König, J. Rehbein
(See online at https://doi.org/10.3762/bjoc.14.228) - Temperature Controlled Selective C-S or C-C Bond Formation: Photocatalytic Sulfonylation versus Arylation of Unactivated Heterocycles Utilizing Aryl Sulfonyl Chlorides. Org. Lett. 2018, 20, 648-651
S. K. Pagire, A. Hossain, O. Reiser
(See online at https://doi.org/10.1021/acs.orglett.7b03790) - Transition metal- and photoredox-catalyzed valorisation of lignin subunits. Green Chem. 2018, 20, 4844-4852
A. Das, B. König
(See online at https://doi.org/10.1039/C8GC02073F) - Unlocking the Potential of Phenacyl Protecting Groups: CO2-Based Formation and Photocatalytic Release of Caged Amines. J. Org. Chem. 2018, 83, 3738–3745
Elisabeth Speckmeier, Michael Klimkait, Kirsten Zeitler
(See online at https://doi.org/10.1021/acs.joc.8b00096) - Visible Light-Mediated Decarboxylation Rearrangement Cascade of ωAryl- N-(acyloxy)phthalimides. J. Org. Chem. 2018, 83, 12192-12206
C. Faderl, S. Budde, G. Kachkovskyi, D. Rackl, O. Reiser
(See online at https://doi.org/10.1021/acs.joc.8b01538) - Visible-Light Photocatalysis: Does it make a difference in Organic Synthesis?. Angew. Chem. Int. Ed. 2018, 57, 10034-10072
L. Marzo, S. K. Pagire, O. Reiser, B. König
(See online at https://doi.org/10.1002/anie.201709766) - Visible-Light-Accelerated Copper(II) Catalyzed Regio- and Chemoselective Oxo-Azidation of Vinyl Arenes. Angew. Chem. Int. Ed. 2018, 57, 8288-8292; Angew. Chem. 2018, 130, 8420-8424
A. Hossain, A. Vidyasagar, C. Eichinger, C. Lankes, J. Phan, J. Rehbein, O. Reiser
(See online at https://doi.org/10.1002/anie.201801678 https://doi.org/10.1002/ange.201801678) - Visible-Light-Accelerated Copper(II) Catalyzed Regio- and Chemoselective Oxo-Azidation of Vinyl Arenes. Angew. Chem. Int. Ed. 2018, 57, 8288-8292; Angew. Chem. 2018, 130, 8420-8424
A. Hossain, A. Vidyasagar, C. Eichinger, C. Lankes, J. Phan, J. Rehbein, O. Reiser
(See online at https://doi.org/10.1002/anie.201801678 https://doi.org/10.1002/ange.201801678) - Visible-Light-Mediated Nitration of Protected Anilines. J. Org. Chem. 2018, 83, 2802-2807
S. J. S. Düsel, B. König
(See online at https://doi.org/10.1021/acs.joc.7b03260) - A Retrosynthetic Approach for Photoredox Catalysis
D. Petzold, M. Giedyk, A. Chatterjee, B. König
(See online at https://doi.org/10.1002/ejoc.201901421) - Alkenylation of unactivated alkyl bromides through visible light photocatalysis. Chem. Commun. 2019, 55, 107-110
Q.–Q. Zhou, S.J.S. Düsel, L.-Q. Lu, B. König, W.-J- Xiao
(See online at https://doi.org/10.1039/c8cc08362b) - Anomalous linear dichroism in bent chromophores of pi-conjugated polymers: departure from the Franck-Condon principle. Phys. Rev. Lett., 2019, 122, 057402
P. Wilhelm, J. Vogelsang, N. Schönfelder, S. Höger, and J. M. Lupton
(See online at https://doi.org/10.1103/physrevlett.122.057402) - Controllable Isomerization of Alkenes by Dual Visible-Light-Cobalt Catalysis. Angew. Chem. Int. Ed. 2019, 58, 5723-5728
Q.-Y. Meng, T. E. Schirmer, K. Katou, B. König
(See online at https://doi.org/10.1002/anie.201900849) - Copper’s rapid ascent in visible-light photoredox catalysis. Science 2019, 364, eaav9713
A. Hossain, A. Bhattacharyya, O. Reiser
(See online at https://doi.org/10.1126/science.aav9713) - Determination of Rea#ction Quantum Yields: LED Based Setup with Better 5 % Precision. EPA Newsletter, June 2019, pp. 51-69
Henrieta Volfova, Qi Hu, and Eberhard Riedle
- Direct catalytic transformation of white phosphorus into arylphosphines and phosphonium salts. Nat. Catal. 2019, 2, 1101–1106
U. Lennert, P. B. Arockiam, V. Streitferdt, D. Scott, C. Rödl, R. Gschwind, R. Wolf
(See online at https://doi.org/10.1038/s41929-019-0378-4) - Enantioselective Visible Light-mediated Formation of 3- Cyclopropylquinolones via Triplet-sensitized Deracemization. Angew. Chem. Int. Ed. 2019, 131 (11), 3576-3579
A. Tröster, A. Bauer, C. Jandl, T. Bach
(See online at https://doi.org/10.1002/ange.201814193) - Impact of visible-light photoredox catalysis on traditional synthetic protocols. Photochemistry, Volume 47
Simon J. S. Düsel und Burkhard König
(See online at https://doi.org/10.1039/9781788016520-00326) - Metal-free Semiconductor Photocatalysis for sp2 C-H Functionalization with Molecular Oxygen. ChemCatChem 2019, 11, 703-706
M. Zheng, I. Ghosh, B. König, X. Wang
(See online at https://doi.org/10.1002/cctc.201801948) - Narobe, Rok - Photocatalytic Oxidative Iodination of Electron‐Rich Arenes. Adv. Synth. Catal. 2019, 361 (17), 3998-4004
R. Narobe, S. Düsel, J. Iskra, B. König
(See online at https://doi.org/10.1002/adsc.201900298) - Organic Dyes in Photocatalytic Reductive C–H Arylations. In Science of Synthesis: Photocatalysis in Organic Synthesis, ed. B. König Publisher: Thieme, 2019
I. Ghosh
(See online at https://doi.org/10.1055/sos-SD-229-00250) - Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes. Science, 2019, 365, 360-366
I. Ghosh, J. Khamrai, A. Savateev, N. Shlapakov, M. Antonietti, B. König
(See online at https://doi.org/10.1126/science.aaw3254) - Photocarboxylation of Benzylic C-H Bonds. J. Am. Chem. Soc. 2019, 141, 11393-11397
Q.-Y. Meng, T. E. Schirmer, A. L. Berger, K. Donabauer, B. König
(See online at https://doi.org/10.1021/jacs.9b05360) - Photocarboxylation of Benzylic C–H Bonds. J. Am. Chem. Soc. 2019, 141, 11393-11397
Q.-Y. Meng, T. E. Schirmer, A. L. Berger, K. Donabauer, B. König
(See online at https://doi.org/10.1021/jacs.9b05360) - Photocatalytic carbanion generation from C–H bonds – reductant free Barbier/Grignard-type reactions. Chem. Sci. 2019, 10, 10991-10996
A. L. Berger, K. Donabauer, B. König
(See online at https://doi.org/10.1039/c9sc04987h) - Photocatalytic carbanion generation – benzylation of aliphatic aldehydes to secondary alcohols. Chem. Sci. 2019, 10, 5162-5166
K. Donabauer, M. Maity, A. L. Berger, G. S. Huff, S. Crespi, B. König
(See online at https://doi.org/10.1039/c9sc01356c) - Photocatalytic Oxidative Iodination of Electron‐Rich Arenes. Adv. Synth. Catal. 2019, 361 (17), 3998-4004
Rok Narobe, Simon J. S. Düsel, Jernej Iskra und Burkhard König
(See online at https://doi.org/10.1002/adsc.201900298) - Practical Aspects of Photocatalysis. Bookchapter in Science of Synthesis, Photocatalysis in Organic Synthesis; König, B., Ed. Thieme, 2019
Elisabeth Speckmeier, Kirsten Zeitler
(See online at https://doi.org/10.1055/sos-SD-229-00059) - Site-Selective, Remote sp3 C-H Carboxylation Enabled by the Merger of Photoredox and Nickel Catalysis. Chem. Eur. J. 2019, 25, 9001-9005
B. Sahoo, P. Bellotti, F. Juliá-Hernández, Q.-Y. Meng, S. Crespi, B. König, R. Martin
(See online at https://doi.org/10.1002/chem.201902095) - Triplet-sensitised di-π-methane rearrangement of N-substituted 2- azabarrelenones. Chem. Commun. 2019, 55, 302-305
A. Tröster, T. Bach
(See online at https://doi.org/10.1039/C8CC08704K) - Visible Light Mediated Liberation and in situ Conversion of Fluorophosgene. Chem. Eur. J. 2019, 25, 361-366
D. Petzold, P. Nitschke, F. Brandl, V. Scheidler, B. Dick, R. M. Gschwind, B. König
(See online at https://doi.org/10.1002/chem.201804603) - Visible light-mediated photo-oxygenation of arylcyclohexenes. Org. Chem. Front. 2019, 6, 2877–2883
Patrick Bayer, Josef Schachtner, Michal Májek, Axel Jacobi von Wangelin
(See online at https://doi.org/10.1039/C9QO00493A) - Visible light-mediated photo-oxygenation of arylcyclohexenes. Organic Chemistry Frontiers 2019, 6, 2877-2833
Patrick Bayer, Josef Schachtner, Michal Majek, Axel Jacobi von Wangelin
(See online at https://doi.org/10.1039/C9QO00493A) - Visible Light-Mediated Synthesis of Enantiopure g-Cyclobutane Amino and 3-(Aminomethyl)-5-phenylpentanoic Acids. Adv. Synth. Catal. 2019, 361, 1400-1407
S. Kerres, E. Plut. S. Malcherek, J. Rehbein, O. Reiser
(See online at https://doi.org/10.1002/adsc.201801413) - Visible-Light-Mediated Regioselective Chlorosulfonylation of Alkenes and Alkynes: Introducing the Cu(II) Complex [Cu(dap)Cl2] to Photochemical ATRA Reactions. ACS Catal. 2019, 9, 1103-1109
A. Hossain, S. Engl, E. Lutsker, O. Reiser
(See online at https://doi.org/10.1021/acscatal.8b04188) - Visible‐Light‐Mediated Synthesis of β‐Chloro Ketones from Aryl Cyclopropanes. Angew. Chem. Int. Ed. 2019, 58, 8577-8580. (Communication)
D. Petzold, P. Singh, F. Almqvist, B. König
(See online at https://doi.org/10.1002/anie.201902473) - Homo-FRET in π-Conjugated Polygons: Intermediate-Strength Dipole- Dipole Coupling Makes Energy Transfer Reversible. Nano Lett. 2020, 19, 5483-5488
P. Wilhelm, J. Vogelsang, S. Höger, and J. M. Lupton
(See online at https://doi.org/10.1021/acs.nanolett.9b01998) - Homogenous visible light mediated transition metal catalysis other than Ruthenium and Iridium. In: B. König, (Ed.): Chemical Photocatalysis, 2nd Edition, DeGruyter, 2020
L. Traub, O. Reiser
(See online at https://doi.org/10.1515/9783110576764-009) - Oxidative Photochlorination of Electron‐Rich Arenes via in situ Bromination. Eur. J. Org. Chem. 2020, 10, 1491-1495
Simon J. S. Düsel und Burkhard König
(See online at https://doi.org/10.1002/ejoc.201900411) - Photocatalytic activation of alkyl chlorides by assembly-promoted single electron transfer in microheterogeneous solutions. Nature Catalysis 2020, 3, 40-47
M. Giedyk, R. Narobe, S. Weiß, D. Touraud, W. Kunz, B. König
(See online at https://doi.org/10.1038/s41929-019-0369-5) - Ultrafast Single-Molecule Fluorescence Measured by Femtosecond Double-Pulse Excitation Photon Antibunching. Nano Lett. 2020, 20 (2), 1074-1079
J. Schedlbauer, P. Wilhelm, L. Grabenhorst, M.E. Federl, B. Lalkens, F. Hinderer, U. Scherf, S. Höger, P. Tinnefeld, S. Bange, J. Vogelsang, and J. M. Lupton
(See online at https://doi.org/10.1021/acs.nanolett.9b04354)