Molecular Alloys: The Transition Metal Compounds [Ma(M'R)b(M''R)c] Containing Organometallic Group-12/13 Ligands

• Applicants: Professor Dr. Roland A. Fischer; Professor Dr. Gernot Frenking
• Subject Area: Inorganic Molecular Chemistry - Synthesis and Characterisation
• Term: from 2009 to 2021
• Project identifier: Deutsche Forschungsgemeinschaft (DFG) - Project number 117432385

• Final Report Year: 2021

Final Report Abstract

No abstract available

Publications

• "The Organozinc Rich Compounds [Cp*M(ZnR)5] (M = Fe, Ru; R = Cp*, Me, Cl, Br)." Inorg. Chem. 2013, 52 (12), 7152-7160
  Molon, M.; Gemel, C.; Seidel, R. W.; Jerabek, P.; Frenking, G.; Fischer, R. A.
  (See online at https://doi.org/10.1021/ic400741b)
• "A Novel Concept for the Synthesis of Multiply Doped Gold Clusters [(M@AunM'm)Lk]q+." Angew. Chem., Int. Ed. 2014, 53 (17), 4327-4331
  Puls, A.; Jerabek, P.; Kurashige, W.; Foerster, M.; Molon, M.; Bollermann, T.; Winter, M.; Gemel, C.; Negishi, Y.; Frenking, G.; Fischer, R. A.
  (See online at https://doi.org/10.1002/anie.201310436)
• "Hume-Rothery Phase-Inspired Metal-Rich Molecules: Cluster Expansion of [Ni(ZnMe)6(ZnCp*)2] by Face Capping with Ni0(η6-toluene) and NiI(η5-Cp*)." Inorg. Chem. 2014, 53 (19), 10403-10411
  Molon, M.; Gemel, C.; Jerabek, P.; Trombach, L.; Frenking, G.; Fischer, R. A.
  (See online at https://doi.org/10.1021/ic5014335)
• "The Intermetalloid Cluster [(Cp*AlCu)6H4], Embedding a Cu6 Core Inside an Octahedral Al6 Shell: Molecular Models of Hume-Rothery Nanophases." Angew. Chem., Int. Ed. 2014, 53 (30), 7943-7947
  Ganesamoorthy, C.; Wessing, J.; Kroll, C.; Seidel, R. W.; Gemel, C.; Fischer, R. A.
  (See online at https://doi.org/10.1002/anie.201402149)
• "The σ-Aromatic Clusters [Zn3]+ and [Zn2Cu]: Embryonic Brass." Angew. Chem., Int. Ed. 2015, 54 (14), 4370-4374
  Freitag, K.; Gemel, C.; Jerabek, P.; Oppel, M. I.; Seidel, R. W.; Frenking, G.; Banh, H.; Dilchert, K.; Fischer, R. A.
  (See online at https://doi.org/10.1002/anie.201410737)
• "Atom-Precise Organometallic Zinc Clusters." Angew. Chem., Int. Ed. 2016, 55 (10), 3285-3289
  Banh, H.; Dilchert, K.; Schulz, C.; Gemel, C.; Seidel, R. W.; Gautier, R.; Kahlal, S.; Saillard, J.-Y.; Fischer, R. A.
  (See online at https://doi.org/10.1002/anie.201510762)
• "Embryonic brass: pseudo two electron Cu/Zn clusters." Chem. Sci. 2018, 9 (48), 8906-8913
  Banh, H.; Hornung, J.; Kratz, T.; Gemel, C.; Poethig, A.; Gam, F.; Kahlal, S.; Saillard, J.-Y.; Fischer, R. A.
  (See online at https://doi.org/10.1039/c8sc03902j)
• "The Mackay-Type Cluster [Cu43Al12](Cp*)12: Open-Shell 67-Electron Superatom with Emerging Metal-Like Electronic Structure." Angew. Chem., Int. Ed. 2018, 57 (44), 14630-14634
  Wessing, J.; Ganesamoorthy, C.; Kahlal, S.; Marchal, R.; Gemel, C.; Cador, O.; Da Silva, A. C. H.; Da Silva, J. L. F.; Saillard, J.-Y.; Fischer, R. A.
  (See online at https://doi.org/10.1002/anie.201806039)
• "All-zinc coordinated nickel-complexes as molecular mimics for NiZn catalyst surfaces, a density functional theory study." Dalton Trans. 2019, 48 (31), 11743-11748
  Hornung, J.; Muhr, M.; Gemel, C.; Fischer, R. A.
  (See online at https://doi.org/10.1039/C9DT02005E)
• "Contrasting Structure and Bonding of a Copper-Rich and a Zinc-Rich Intermetalloid Cu/Zn Cluster." Inorg. Chem. 2020, 59 (13), 9077-9085
  Schuetz, M.; Muhr, M.; Freitag, K.; Gemel, C.; Kahlal, S.; Saillard, J.-Y.; Da Silva, A. C. H.; Da Silva, J. L. F.; Faessler, T. F.; Fischer, R. A.
  (See online at https://doi.org/10.1021/acs.inorgchem.0c00943)